Ammonium tetrathiovanadate
| Names | |
|---|---|
| Other names
Ammonium tetrathiovanadate(V)
| |
| Identifiers | |
| Properties | |
| H12N3S4V | |
| Molar mass | 233.30 g·mol−1 |
| Appearance | violet crystals |
| Density | g/cm3 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
| |
Ammonium tetrathiovanadate is a chemical compound with the chemical formula (NH4)3VS4.[1][2]
Physical properties
[edit]Ammonium tetrathiovanadate forms violet crystals of orthorhombic symmetry.[3]
Chemical properties
[edit]Like other ammonium salts, ammonium tetrathiovanadate decomposes when heated:[4]
- (NH4)3VS4 → 6NH3↑ + 3H2S↑ + V2S5
- V2S5 → V2S3 + 2S
References
[edit]- ^ "CAS 14693-56-2 Ammonium tetrathiovanadate(v),99 - Alfa Chemistry". alfa-chemistry.com. Retrieved 24 December 2024.
- ^ Scott, C. E.; Embaid, B. P.; Gonzalez-Jimenez, F.; Hubaut, R.; Grimblot, J. (1 March 1997). "Behavior of Iron–Vanadium Sulfide Catalysts for Hydrotreating Reactions". Journal of Catalysis. 166 (2): 333–339. doi:10.1006/jcat.1997.1526. ISSN 0021-9517. Retrieved 24 December 2024.
- ^ Donnay, Joseph Désiré Hubert (1973). Crystal Data: Inorganic compounds. National Bureau of Standards. p. 200. Retrieved 24 December 2024.
- ^ Prasad, T. P.; Müller, A. (December 1976). "Thermal decompositions of (NH4)2WSe4 and (NH4)3VS4 under normal and reduced nitrogen pressures". Journal of Thermal Analysis and Calorimetry. 10 (3): 369–373. doi:10.1007/BF01909888. Retrieved 24 December 2024.