Ammonium perbromate

Ammonium perbromate
Names
	IUPAC name Azanium perbromate
	Other names Ammonium perbromate
Identifiers
CAS Number	28037-93-6;
3D model (JSmol)	Interactive image;
ChemSpider	13687751;
PubChem CID	23293222;
	InChI InChI=1S/BrHO4.H3N/c2-1(3,4)5;/h(H,2,3,4,5);1H3 Key: MMQCMMVCGMXMPN-UHFFFAOYSA-N;
	SMILES [NH4+].[O-]Br(=O)(=O)=O;
Properties
Chemical formula	NH4BrO4
Molar mass	161.94 g/mol
Solubility in water	soluble
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Ammonium perbromate is an inorganic chemical compound with the formula NH₄ BrO₄. It shares similar properties to ammonium perchlorate, but is substantially more difficult to isolate, and has a complex mechanism of decomposition.^[1]^[2]^[3]

Properties

Ammonium perbromate is stable at room temperature, and has solubilities which are similar to ammonium perchlorate. Ammonium perbromate is much less hygroscopic in comparison to ammonium perchlorate, and has been shown to increase in weight when maintained in an atmosphere with high humidity.^[2]

Ammonium perbromate begins to decompose at a temperature between 170 and 180 Celsius, and has been observed to explode on occasion.^[2]

References

^ Hull, Katherine L.; Cairns, Amy J.; Haq, Marium (19 February 2019). "Bromate Oxidation of Ammonium Salts: In Situ Acid Formation for Reservoir Stimulation". Inorganic Chemistry. 58 (5): 3007–3014. doi:10.1021/acs.inorgchem.8b02891. PMID 30777427. Retrieved 31 August 2024.
^ ^a ^b ^c Keith, James N.; Solomon, Irving J. (16 May 1969). "Ammonium Perbromate". Inorganic Chemistry. 9 (6): 1560–1561. doi:10.1021/ic50088a051. Retrieved 31 August 2024.
^ Pisarenko, Aleksey N.; Young, Robert; Quiñones, Oscar; Vanderford, Brett J.; Mawhinney, Douglas B. (22 July 2011). "Two New Methods of Synthesis for the Perbromate Ion: Chemistry and Determination by LC-MS/MS". Inorganic Chemistry. 50 (18): 8691–8693. doi:10.1021/ic201329q. PMID 21780765. Retrieved 31 August 2024.

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[1] Hull, Katherine L.; Cairns, Amy J.; Haq, Marium (19 February 2019). "Bromate Oxidation of Ammonium Salts: In Situ Acid Formation for Reservoir Stimulation". Inorganic Chemistry. 58 (5): 3007–3014. doi:10.1021/acs.inorgchem.8b02891. PMID 30777427. Retrieved 31 August 2024.

[inorg1969-2] Keith, James N.; Solomon, Irving J. (16 May 1969). "Ammonium Perbromate". Inorganic Chemistry. 9 (6): 1560–1561. doi:10.1021/ic50088a051. Retrieved 31 August 2024.

[3] Pisarenko, Aleksey N.; Young, Robert; Quiñones, Oscar; Vanderford, Brett J.; Mawhinney, Douglas B. (22 July 2011). "Two New Methods of Synthesis for the Perbromate Ion: Chemistry and Determination by LC-MS/MS". Inorganic Chemistry. 50 (18): 8691–8693. doi:10.1021/ic201329q. PMID 21780765. Retrieved 31 August 2024.

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