Scandium triiodide

Scandium triiodide
Names
	IUPAC name Scandium triiodide
	Other names Scandium(III) iodide; Scandium(3+) triiodide; Triiodoscandium
Identifiers
CAS Number	14474-33-0 ;
3D model (JSmol)	Interactive image;
ECHA InfoCard	100.034.956
EC Number	238-469-0;
PubChem CID	4420285;
UNII	QVJ18SK04T ;
CompTox Dashboard (EPA)	DTXSID00932397 ;
	InChI InChI=1S/3HI.Sc/h3*1H;/q;;;+3/p-3 Key: HUIHCQPFSRNMNM-UHFFFAOYSA-K;
	SMILES [Sc](I)(I)I;
Properties
Chemical formula	ScI3
Molar mass	425.66
Appearance	Yellowish solid
Melting point	920 °C (1,690 °F; 1,190 K)
Related compounds
Other anions	Scandium fluoride ; Scandium chloride ; Scandium bromide
Other cations	Yttrium(III) iodide ; Lutetium(III) iodide
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Scandium triiodide, also known as scandium iodide, is an inorganic compound with the formula ScI₃ and is classified as a lanthanide iodide. This salt is a yellowish powder.^[1] It is used in metal halide lamps together with similar compounds, such as caesium iodide, because of their ability to maximize emission of UV and to prolong bulb life. The maximized UV emission can be tuned to a range that can initiate photopolymerizations.^[2]

Scandium triiodide adopts a structure similar to that of iron trichloride (FeCl₃), crystallizing into a rhombohedral lattice. Scandium has a coordination number of 6, while iodine has a coordination number of 3 and is trigonal pyramidal.^[3]

The purest scandium triiodide is obtained through direct reaction of the elements:^[1]

2 Sc + 3 I₂ → 2 ScI₃

Alternatively, but less effectively, one can produce anhydrous scandium triiodide by dehydrating ScI₃(H₂O)₆.

Further information

Tomasz Mioduski, Cezary Gumiski, and Dewen Zeng "Rare Earth Metal Iodides and Bromides in Water and Aqueous Systems. Part 1. Iodides" Journal of Physical and Chemical Reference Data 2012, vol. 41, 013104-1 to 013104-63. doi:10.1063/1.3682093

References

^ ^a ^b Haeberle, N., 1973, Preparation of highly pure lanthanide iodides, Technisch-Wissenschaftliche Abhandlungen der Osram-Gesellschaft, v. 11, p. 285
^ Brabham, D.E., Metal halide lamp for curing adhesives. U.S. Patent 6,888,312, March 1, 2011
^ Men'kov, A. A., Komissarova, L. N., 1964, X-ray study of scandium iodide, Zhurnal Neorganicheskoi Khimii, v. 9, p. 766

[Haeb-1] Haeberle, N., 1973, Preparation of highly pure lanthanide iodides, Technisch-Wissenschaftliche Abhandlungen der Osram-Gesellschaft, v. 11, p. 285

[2] Brabham, D.E., Metal halide lamp for curing adhesives. U.S. Patent 6,888,312, March 1, 2011

[3] Men'kov, A. A., Komissarova, L. N., 1964, X-ray study of scandium iodide, Zhurnal Neorganicheskoi Khimii, v. 9, p. 766

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