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Arsenide bromide

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Arsenide bromides or bromide arsenides are compounds containing anions composed of bromide (Br−) and arsenide (As3−). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide iodides, phosphide bromides, and antimonide bromides.

List

[edit]
formula system space group unit cell Å volume density comment ref
(Ca2−x□x)(As1−xBr1+x) Ca2AsBr cubic a=6.05 3.47 yellow, or dark brown [1][2]
Ca3AsBr3 cubic Pm3 a=5.91 3.48 colourless or yellow [1][2]
Cu6AsS5Br cubic F43m a=9.8763 4.80 [3][4]
(Ge38As8)+8⋅8 I− cubic Pm3n a=10.625 5.71 semiconductor resistivity 1 Ω cm; band gap 0.9 eV; silvery grey [5]
I8As21Ge25 cubic Pm3n a=10.5963 Z=1 1189.77 6.143 colourless [6]
Cd2As3Br monoclinic C2/c a = 8.281, b = 9.411, c = 7.993, β = 101.49°, z = 4 5.76 black [7][8]
Cd4As2Br3 cubic Pa3 a=12.61 5.51 semiconductor band gap 1.8 eV [9]
Cd4PAsBr3 cubic Pa3 a=12.521 5.38 [10][4]
Cd4As2I1.5Br1.5 cubic Pa3 a=12.83 [11][4]
La3AsBr3 cubic I4132 a=12.09 5.50 [12]
Pr3AsBr3 cubic I4132 a=12.02 5.64 [12]
Hg2As3Br monoclinic C2/c a = 8.0914, b = 9.300, c = 8.1084, β = 99.323°, z = 4 7.79 black [7]
Hg4As2Br3 cubic Pa3 a=12.610 Z=8 2012.4 5.54 7.90 red; dark grey [13][14]
Hg19As10Br18 triclinic P1 a = 11.262, b = 11.352, c = 12.309, α = 105.724, β = 105.788, γ = 109.078° 1314.3 dark brown [15]
(HgBr2)3(As4S4)2 monoclinic P21/c a = 9.593, b = 11.395, c = 13.402, β = 107.27, Z = 2 1399 [16]
Hg3AsS4Br hexagonal P63mc a = 7.430, c = 9.364 Z=2 [17]
(Hg6As4)[TiBr6]Br cubic Pa3 a= 1230.9 [18]
[Hg6As4](CrBr6)Br cubic Pa a=12.275 [Hg6As4]4+ framework with 2 kinds of cavity; band gap 1.5 eV [19]
[Hg6As4](FeBr6)Hg0.6 cubic Pa a=12.332 [Hg6As4]4+ framework with 2 kinds of cavity; band gap 1.5 eV [19]
[Hg6As4](CuBr3)2 monoclinic I2/a a = 14.884, b = 9.358, c = 20.413, β=92.88°, Z = 6 dark red [20]
[Hg11As4](GaBr4)4 monoclinic C2/m [21]
Hg3AsSe4Br hexagonal P63mc a = 7.707, c = 9.47 Z=2 [17]
(Hg2Cd2As2Br)Br orthorhombic Pmma a = 8.791, b = 4.701, c = 9.779, Z=2 404.2 7.688 dark red [22]
(Hg6As4)(CdBr6) cubic Pa3 a=12.3738 Z=4 1894.6 7.345 red; air stable; band gap 1.94 [23]
[Hg6As4][InBr6]Br cubic Pa3 a=12.3511 Z=4 1884.2 dark red [24]
[Hg4As2](InBr3.5As0.5) Hexagonal P63/mmc a = 7.7408, c = 12.535, Z=2 650.47 [25]
[Hg6As4Br3](SnBr3) cubic P213 a=12.383 Z=4 [26]
[Hg6As4][YbBr6]Br cubic Pa3 a=12.362 Z=4 1889.1 7.860 dark red [27]
Hg9As4Bi2Br12 tetragonal P43 a=10.865 b=10.865 c=28.357 Z=4 3347.5 6.91 orange [28]

References

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  2. ^ a b Hadenfeldt, Claus (1976-04-01). "Darstellung und Eigenschaften von Ca 2 AsBr, Sr 2 AsCl und Ca 3 AsBr 3 .: Preparation and Properties of Ca 2 AsBr, Sr 2 AsCl, and Ca 3 AsBr 3". Zeitschrift für Naturforschung B. 31 (4): 408–410. doi:10.1515/znb-1976-0403. ISSN 1865-7117. S2CID 95122668.
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  18. ^ Beck, Johannes; Neisel, Udo (2000). "Synthese, Kristallstrukturen und Magnetismus von (Hg6As4)[MoCl6]Cl, (Hg6As4)[TiCl6]Cl und (Hg6As4)[TiBr6]Br". Zeitschrift für Anorganische und Allgemeine Chemie. 626 (7): 1620–1626. doi:10.1002/1521-3749(200007)626:7<1620::AID-ZAAC1620>3.0.CO;2-R.
  19. ^ a b Olenev, Andrei V.; Oleneva, Olga S.; Lindsjö, Martin; Kloo, Lars A.; Shevelkov, Andrei V. (2003-07-21). "Coordinated and Clathrated Guests in the [Hg6As4]4+ Bicompartmental Framework: Synthesis, Crystal and Electronic Structure, and Properties of the Novel Supramolecular Complexes [Hg6As4](CrBr6)Br and [Hg6As4](FeBr6)Hg0.6". Chemistry - A European Journal. 9 (14): 3201–3208. doi:10.1002/chem.200204687. PMID 12866063.
  20. ^ Oleneva, Olga S.; Olenev, Andrei V.; Dikarev, Evgeny V.; Shevelkov, Andrei V. (June 2005). "Solid State Supramolecular Complexes [Hg6As4](CuX3)2 (X = Cl, Br): One-Dimensional Helical Guest in a Three-Dimensional Host Framework". Journal of Cluster Science. 16 (2): 273–285. doi:10.1007/s10876-005-4548-y. ISSN 1040-7278. S2CID 95453360.
  21. ^ Borisov, S. V.; Pervukhina, N. V.; Magarill, S. A. (February 2020). "Crystallographic Analysis and Symmetry Generation for Some Structures with [As2] and [Hgn] (n = 2, 3) Cluster Groups". Journal of Structural Chemistry. 61 (2): 259–266. doi:10.1134/S0022476620020109. ISSN 0022-4766. S2CID 220540955.
  22. ^ Zou, Jian-Ping; Guo; Chen, Wen-Tong; Liu, Xi; Fu, Ming-Lai; Zhang; Huang, Jin-Shun (2006-08-01). "Synthesis, Crystal and Band Structures, and Optical Properties of a New Quaternary Metal Pnictidehalide: (Hg 2 Cd 2 As 2 Br)Br". Inorganic Chemistry. 45 (16): 6365–6369. doi:10.1021/ic060503r. ISSN 0020-1669. PMID 16878947.
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  24. ^ Deiseroth, Hans-Jörg; Schlirf, Jens; Reiner, Christof (June 2009). "Crystal structure of tetraarsenidohexamercury hexabromoindate bromide, [Hg6As4][InBr6]Br and tetraantimonidohexamercury hexabromoindate bromide, [Hg6Sb4][InBr6]Br". Zeitschrift für Kristallographie - New Crystal Structures. 224 (2): 167–168. doi:10.1524/ncrs.2009.0075. S2CID 201061929.
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  27. ^ Olenev, Andrei V.; Shestimerova, Tatiana A.; Schnelle, Walter; Shevelkov, Andrei V. (July 2005). "Synthesis, Structure, and Properties of [Hg6As4][YbBr6]Br, a Supramolecular Assembly Featuring a Discrete [YbBr6]3− Anion". Zeitschrift für anorganische und allgemeine Chemie (in German). 631 (9): 1698–1701. doi:10.1002/zaac.200500059. ISSN 0044-2313.
  28. ^ Puff, H.; Grönke, M.; Kilger, B.; Möltgen, P. (November 1984). "Darstellung und Struktur des Mercuroarsoniumbromo-bismutats [Hg7(HgBr)2As4] [Bi2Br10]". Zeitschrift für anorganische und allgemeine Chemie (in German). 518 (11): 120–128. doi:10.1002/zaac.19845181112. ISSN 0044-2313.
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