User:SvenjaHffmstr/Sandbox

Sand filters are used as a step in the water treatment process of water purification.

There are three main types; rapid (gravity) sand filters, upward flow sand filters and slow sand filters. All three methods are used extensively in the water industry throughout the world. The first two require the use of flocculant chemicals to work effectively while slow sand filters can produce very high quality water free from pathogens, taste and odour without the need for chemical aids^[1]. Sand filters can, apart from being used in water treatment plats, be used for water purification in singular households as they use materials which are available for most people^[2].

History

The history of seperation techniques reaches far back and, already during ancient periods, filter materials have found application. Rushes and genista were for instance used as filling of sieving vessels to seperate solid and liquid materials. Furthermore, the egyptians utilized porous clay vessels to filter drinking water, wine and other liquids.^[3]

Sand Bed Filtration Concept

A sand bed filter is a kind of depth filter. Broadly, there are two types of filter for separating particulate solids from fluids:

Surface filters, where particulates are captured on a permeable surface
Depth filters, where particulates are captured within a porous body of material.^[4]

In addition, there are passive and active devices for causing solid-liquid separation such as settling tanks, self-cleaning screen filters, hydrocyclones and centrifuges.^[4]

There are several kinds of depth filter, some employing fibrous material and others employing granular materials. Sand bed filters are an example of a granular loose media depth filter. They are usually used to separate small amounts (<10 parts per million or <10 g per cubic metre) of fine solids (<100 micrometres) from aqueous solutions.^[5]^{: 302–303} In addition, they are usually used to purify the fluid rather than capture the solids as a valuable material. Therefore they find most of their uses in liquid effluent (wastewater) treatment.

Particulate Solids Capture Mechanisms

Sand bed filters work by providing the particulate solids with many opportunities to be captured on the surface of a sand grain. As fluid flows through the porous sand along a tortuous route, the particulates come close to sand grains. They can be captured by one of several mechanisms:

Direct collision
Van der Waals or London force attraction
Surface charge attraction
Diffusion.^[4]

In addition, particulate solids can be prevented from being captured by surface charge repulsion if the surface charge of the sand is of the same sign (positive or negative) as that of the particulate solid. Furthermore, it is possible to dislodge captured particulates although they may be re-captured at a greater depth within the bed. Finally, a sand grain that is already contaminated with particulate solids may become more attractive or repel addition particulate solids. This can occur if by adhering to the sand grain the particulate loses surface charge and becomes attractive to additional particulates or the opposite and surface charge is retained repelling further particulates from the sand grain.

In some applications it is necessary to pre-treat the effluent flowing into a sand bed to ensure that the particulate solids can be captured. This can be achieved by one of several methods:

Adjusting the surface charge on the particles and the sand by changing the pH
Coagulation – adding small, highly charged cations (aluminium 3+ or calcium 2+ are usually used)
Flocculation – adding small amounts of charge polymer chains which either form a bridge between the particulate solids (making them bigger) or between the particulate solids and the sand.

Operating Regimes

They can be operated either with upward flowing fluids or downward flowing fluids the latter being much more usual. For downward flowing devices the fluid can flow under pressure or by gravity alone. Pressure sand bed filters tend to be used in industrial applications and often referred to as rapid sand bed filters. Gravity fed units are used in water purification especially drinking water and these filters have found wide use in developing countries (slow sand filters).

Overall, there are several categories of sand bed filter:

rapid (gravity) sand filters
rapid (pressure) sand bed filters
upflow sand filters
slow sand filters.

The sketch illustrates the general structure of a rapid pressure sand filter. The filter sand takes up most space of the chamber. It sits either on a nozzle floor or on top of a drainage system which allows the filtered water to exit. The pre-treated raw water enters the filter chamber on the top, flows through the filter medium and the effluent drains through the drainage system in the lower part. Large process plants have also a system implemented to evenly distribute the raw water to the filter. In addition, a distribution system controlling the air flow is usually included. It allows a constant air and water distribution and prevents too high water flows in specific areas. A typical grain distribution exits due to the frequent backwashing. Grains with smaller diameter are dominant in the upper part of the sand layer while coarse grain dominates in the lower parts.

Two processes influencing the functionality of a filter are ripening and regeneration.
At the beginning of a new filter run, the filter efficiency increases simultaneously with the number of captured particles in the medium. This process is called filter ripening. During filter ripening the effluent might not meet quality criteria and must be reinjected at previous steps in the plant^[6]. Regeneration methods allow the reuse of the filter medium. Accumulated solids from the filter bed are removed^[6]. During backwashing, water (and air) is pumped backwards through the filter system. Backwash water may partially be reinjected in front of the filter process and generated sewage needs to be discarded. The backwashing time is determined by either the turbidity value behind the filter, which must not exceed a set threshold, or by the head loss across the filter medium, which must also not exceed a certain value.

Rapid Pressure Sand Bed Filter Design

**Rapid pressure filter** 1=raw water, 2=filtered water, 3=tank, 4=inlet flushing water, 5=outlet flushing water, 6=retraction line, 7=scavenging air, 8=injector, 9=supporting layer, 10=filter sand, 11=flushing funnel, 12=ventilation

Smaller sand grains provide more surface area and therefore a higher decontamination of the inlet water, but it also requires more pumping energy to drive the fluid through the bed. A compromise is that most rapid pressure sand bed filters use grains in the range 0.6 to 1.2 mm although for specialist applications other sizes may be specified. Larger feed particles (>100 micrometres) will tend to block the pores of the bed and turn it into a surface filter that blinds rapidly. Larger sand grains can be used to overcome this problem, but if significant amounts of large solids are in the feed they need to be removed upstream of the sand bed filter by a process such as settling.^[5]^{: 302–303}

The depth of the sand bed is recommended to be around 0.6 - 1.8 m (2–6 ft) regardless of the application. This is linked to the maximum throughput discussed below.^[5]^{: 302–303}

Guidance on the design of rapid sand bed filters suggests that they should be operated with a maximum flow rate of 9 m³/m²/hr (220 US gal/ft²/hr).^[7] Using the required throughput and the maximum flowrate, the required area of the bed can be calculated.

The final key design point is to be sure that the fluid is properly distributed across the bed and that there are no preferred fluid paths where the sand may be washed away and the filter be compromised.

Rapid pressure sand bed filters are typically operated with a feed pressure of 2 to 5 bar(a) (28 to 70 psi(a)). The pressure drop across a clean sand bed is usually very low. It builds as particulate solids are captured on the bed. Particulate solids are not captured uniformly with depth, more are captured higher up with bed with the concentration gradient decaying exponentially.^[5]^{: 302–303}

This filter type will capture particles down to very small sizes, and does not have a true cut off size below which particles will always pass. The shape of the filter particle size-efficiency curve is a U-shape with high rates of particle capture for the smallest and largest particles with a dip in between for mid-sized particles.^[7]

The build-up of particulate solids causes an increase in the pressure lost across the bed for a given flow rate. For a gravity fed bed when the pressure available is constant, the flow rate will fall. When the pressure loss or flow is unacceptable and the filter is not working effectively any longer, the bed is backwashed to remove the accumulated particles. For a pressurized rapid sand bed filter this occurs when the pressure drop is around 0.5 bar. The backwash fluid is pumped backwards through the bed until it is fluidized and has expanded by up to about 30% (the sand grains start to mix and as they rub together they drive off the particulate solids). The smaller particulate solids are washed away with the backwash fluid and captured usually in a settling tank. The fluid flow required to fluidize the bed is typically 3 to 10 m³/m²/hr but not run for long (a few minutes).^[5]^{: 224–235} Small amounts of sand can be lost in the backwashing process and the bed may need to be topped up periodically.

Slow Sand Filter Design

As the title indicates, the speed of filtration is changed in the slow sand filter, however, the biggest difference between slow and rapid sand filter, is that the top layer of sand is biologically active, as microbial communities are introduced to the system. The recommended and usual depth of the filter is 0.9 to 1.5 meters. Microbial layer is formed within 10-20 days from the start of the operation. During the process of filtration, raw water can percolate through the porous sand medium, stopping and trapping organic material, bacteria, viruses and cysts such as Giardia and Cryptosporidium. The regeneration procedure for slow sand filters is called scraping and is used to mechanically remove the dried out particles on the filter. However, this process can also be done under water, depending on the individual system. Another limiting factor for the water being treated is turbidity, which is for slow sand filters defined to be 10 NTU (Nephelometric Turbidity Units). Slow sand filters are a good option for limited budget operations as the filtration is not using any chemicals and requires little or no mechanical assistance. However, because of a continuous growing population in communities, slow sand filters are being replaced for rapid sand filters, mostly due to the running period length.

Characteristics of Rapid and Slow Sand Filters ^[6]

Characteristics	Rapid Sand Filter	Slow Sand Filter
Filtration rate [m/h]	5 - 15	0.08 - 0.25
Media effective size [mm]	0.5 - 1.2	0.15 - 0.30
Bed depth [m]	0.6 - 1.8	0.9 - 1.5
Run length	1 - 4 days	1 - 6 months
Ripening period	15 min - 2 h	Several days
Regeneration method	Backwashing	Scraping
Maximum raw-water turbidity	Unlimited with proper pretreatment	10 NTU

Mixed bed filters

Filters can be constructed with different layers, called mixed bed filters. Sand is a common filter material, but anthracite, granular activated carbon (GAC), garnet and ilmenite are also common filter materials. Anthracite is a harder material and has less volatile compared to other coals. Ilmenite and garnet are heavy compared to sand. Garnet consists several minerals, causing a shifting red colour. Ilmenite is an oxide of iron and titanium. GAC can be used in the process of adsorption and filtration at the same time. These materials can be used both alone, or combined with other media. Different combinations give different filter classification. Monomedia is a one layered filter, commonly consisting of sand and is today replaced by newer technology. Deep-bed monomedia is also a one layered filter which consist of either anthracite or GAC. The deep-bed monomedia filter is used when there is a consistent water quality and this gives a longer run time. Dual media (two layered) often contain a sand layer in the bottom with an anthracite or GAC layer on top. Trimedia or mixed media is a filter with three layers. Trimedia often have garnet or ilmenite in the bottom layer, sand in the middle and anthracite at the top.

Uses in Water Treatment

All of these methods are used extensively in the water industry throughout the world. The first three in the list above require the use of flocculant chemicals to work effectively. Slow sand filters produce high quality water without the use of chemical aids.

Passing flocculated water through a rapid gravity sand filter strains out the floc and the particles trapped within it reducing numbers of bacteria and removing most of the solids. The medium of the filter is sand of varying grades. Where taste and odour may be a problem (organoleptic impacts), the sand filter may include a layer of activated carbon to remove such taste and odour.

Sand filters become clogged with floc after a period in use and they are then backwashed or pressure washed to remove the floc. This backwash water is run into settling tanks so that the floc can settle out and it is then disposed of as waste material. The supernatant water is then run back into the treatment process or disposed of as a waste-water stream. In some countries the sludge may be used as a soil conditioner. Inadequate filter maintenance has been the cause of occasional drinking water contamination.

Sand filters are occasionally used in the treatment of sewage as a final polishing stage (see Sewage treatment). In these filters the sand traps residual suspended material and bacteria and provides a physical matrix for bacterial decomposition of nitrogenous material, including ammonia and nitrates, into nitrogen gas.

Sand filters are one of the most useful treatment processes as the filtering process (especially with slow sand filtration) combines within itself many of the purification functions^[8].

Challenges in the Application Process

In the process of water treatment one should be aware of certain factors that might cause serious problems if not treated properly. Afformentioned processes such as filter ripening and backwashing influence not only the water quality but also the time needed for the full treatment. Backwashing reduces also the volume of the effluent. If a certain amount of water has to be deliviered to e.g. a community, this water loss needs to be considered. In addition, backwashing waste needs to be treated or properly disgarded. From the chemical perspective varying raw water qualities and changes in the temperture effect already at the entrance to the plant the efficiency of the treatment process.

Considerable uncertainty is involved regarding models used to construct sand filters. This is due to mathematical assumptions that have to be made such as all grains being spherical. The spherical shape effects the interpretation of the size, since the diameter is different for spherical and non-spherical grains. The packing of the grains within the bed is also depending on the shape of the grains. This then affects the porosity and hydraulic flow^[6].

References

^ "Slow Sand Filtration" (PDF). National Drinking Water Clearinghouse.
^ "Household Sand Filters for Arsenic Removal" (PDF). EAWAG.
^ Anlauf, Harald (2003). "Mechanische Fest/Flüssig-Trennungim Wandel der Zeit". Chemie Ingenieur Technik. 75 (10). doi:10.1002/cite.200303283.
^ ^a ^b ^c Rushton, A, Ward, A S and Holdich, R G (1996). Introduction to Solid-Liquid Filtration and Separation Technology. Wiley VCH. ISBN 978-3-527-28613-3
^ ^a ^b ^c ^d ^e Coulson, J M; Richardson, J F; Backhurst, J R and Harker, J H (1991). Chemical Engineering. Vol.2, 4th Ed. ISBN 0-7506-2942-8.
^ ^a ^b ^c ^d Borchardt, John C. Crittenden ... ; with contributions by James H.; et al. (2012). MWH's water treatment : principles and design (3rd ed. ed.). Hoboken, N.J.: John Wiley & Sons. ISBN 9780470405390. {{cite book}}: |edition= has extra text (help); Explicit use of et al. in: |first1= (help)CS1 maint: multiple names: authors list (link)
^ ^a ^b Ives, K J (1990). "Deep Bed Filtration." Chap. 11 of Solid-Liquid Separation, 3rd Ed., Svarovsky L (ed). Butterworths. ISBN 0-408-03765-2
^ Huisman, L.; Wood, W.E. (1974). Slow sand filtration. Geneva: World Health Organization. ISBN 9241540370.