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User:Praseodymium-141/Terbium compounds

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  • Applications section:

(add information about pure terbium or terbium alloys)


  • Translating some chinese refs.

Did some, not finished.


  • Add pnictides section.

Pnictides

[edit]

All the terbium pnictides form crystals of the cubic crystal system, with the space group of Fm3m.[1][2][3] Terbium phosphide can be obtained by reacting sodium phosphide and anhydrous terbium(III) chloride at 700 to 800˚C.[4] It undergoes a phase transition at 40 GPa from a NaCl-structure to a CsCl-structure.[5] It can be sintered with zinc sulfide to make a green phosphor layer.[6]


  • Add information about other Tb compounds.
  • Compare to other compounds.
  • Check the Oxygenated salts section (probably rename as other inorganic compounds)

Others: here.

  1. ^ "Terbium Phosphide TbP". materialsproject.org. Retrieved 24 December 2021.
  2. ^ Dubey, Ritu; Singh, Sadhna; Kaur, Gurusharan (2021-01-01). "Structural analysis of terbium monopnictides under high pressure". Solid State Communications. 338. doi:10.1016/j.ssc.2021.114465. ISSN 0038-1098.
  3. ^ * D.W. Hafemeister et al. J. Chem. Phys. (1965)
  4. ^ Rowley, Adrian T.; Parkin, Ivan P. (1 January 1993). "Convenient synthesis of lanthanide and mixed lanthanide phosphides by solid-state routes involving sodium phosphide". Journal of Materials Chemistry. 3 (7): 689–692. doi:10.1039/JM9930300689. ISSN 1364-5501. Retrieved 9 January 2022.
  5. ^ Adachi, Takafumi; Shirotani, Ichimin; Hayashi, Junichi; Shimomura, Osamu (28 December 1998). "Phase transitions of lanthanide monophosphides with NaCl-type structure at high pressures". Physics Letters A. 250 (4–6): 389–393. Bibcode:1998PhLA..250..389A. doi:10.1016/S0375-9601(98)00840-8. Retrieved 9 January 2022.
  6. ^ Raffius, G.; Kötzler, J. (7 February 1983). "Field-dependence of the first-order phase transition in terbium phosphide". Physics Letters A. 93 (8): 423–425. Bibcode:1983PhLA...93..423R. doi:10.1016/0375-9601(83)90477-2. ISSN 0375-9601. Retrieved 9 January 2022.