Jump to content

User:Praseodymium-141/Gadolinium acetate

From Wikipedia, the free encyclopedia
Gadolinium acetate
Names
Other names
Gadolinium ethanoate
Identifiers
Properties
Gd(CH3COO)3
Appearance colorless crystal or white powder
Density 1.611 g·cm−3 (hydrate)
9.7 g
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Gadolinium acetate is the acetate salt of the lanthanide element gadolinium, with the chemical formula Gd(CH3COO)3. It is a colorless crystal that is soluble in water and can form a hydrate.[1] Its tetrahydrate has ground state ferromagnetism.[2]

Preparation

[edit]

The tetrahydrate of gadolinium acetate can be crystallized from aqueous solution by reaction of gadolinium oxide and acetic acid:[2]

Gd2O3 + 6 HAc + 5 H2O → [(GdAc3(H2O)2)2]·4H2O

Properties

[edit]

The complex [Gd4(CH3COO)4(acac)8(H2O)4] can be obtained by the reflux reaction of gadolinium acetate and acetylacetone in the presence of triethylamine in methanol solution.[3]

References

[edit]
  1. ^ Справочник химика. Vol. 2 (3-е изд., испр ed.). Л.: Химия. 1971. {{cite book}}: Unknown parameter |agency= ignored (help)
  2. ^ a b Stephan T. Hatscher, Werner Urland (2003). "Unexpected Appearance of Molecular Ferromagnetism in the Ordinary Acetate [Gd(OAc)3(H2O)22]⋅4 H2O". Angewandte Chemie International Edition. 42 (25): 2862–2864. doi:10.1002/anie.200250738. ISSN 1521-3773. Archived from the original on 2020-05-27. Retrieved 2019-02-01.
  3. ^ Fu-Sheng Guo, Ji-Dong Leng, Jun-Liang Liu, Zhao-Sha Meng, Ming-Liang Tong (2012-01-02). "Polynuclear and Polymeric Gadolinium Acetate Derivatives with Large Magnetocaloric Effect". Inorganic Chemistry. 51 (1): 405–413. doi:10.1021/ic2018314. ISSN 0020-1669. Retrieved 2019-02-01.{{cite journal}}: CS1 maint: multiple names: authors list (link)

Category:Gadolinium compounds Category:Acetates