User:Graeme Bartlett/sulfate tellurite
Sulfate tellurites are mixed anion compounds that contain sulfate and tellurite ions.
Sulfate tellurites are of research interest to find non-linear optical materials. Desirable characteristics are high non-linearity, high transparency across a wide wavelength range, able to withstand high laser power, resistance to heat, and a large enough birefringence.[1]
List
[edit]| formula | fw | crystal system | space group | unit cell | volume | density | comment | reference |
|---|---|---|---|---|---|---|---|---|
| Cu3(TeO4)(SO4)·H2O | orthorhombic | Pnma | a=15.974 b=6.3468 c=7.256 | [2] | ||||
| Zn4(Te3O7)2(SO4)2(H2O) | 1461.22 | monoclinic | C2/c | a=22.845 b=5.459 c=15.655 beta=99.598 Z=4 | 1925.1 | 5.042 | white | [3] |
| Ga2(TeO3)(SO4)(OH)2 | 445.12 | monoclinic | P21/m | a=4.9825 b=9.752 c=6.974 beta=93.55 Z=2 | 338.21 | 4.371 | white | [3] |
| Y2(Te4O10)(SO4) | triclinic | P1 | a =6.8140 b =9.3229 c =9.8640, α =89.835° β =72.490° γ =88.200° Z=2 | 597.28 | 5.251 | band gap 4.1 eV | [1] | |
| Y3(TeO3)2(SO4)2(OH)(H2O) | monoclinic | P21/m | a =5.4419 b =15.288 c =7.9709 β =99.20° Z=2 | 654.6 | 4.287 | band gap 4.4 eV | [1] | |
| Y2Co(TeO3)2(SO4)2 | triclinic | P1 | [4] | |||||
| Y2Cu(TeO3)2(SO4)2 | light green | [5] | ||||||
| In2(TeO3)2(SO4)(H2O) | 694.92 | monoclinic | C2/c | a=17.636 b=6.7576 c=16.455 beta=107.394 Z=8 | 1871.3 | 4.933 | colourless | [3] |
| Sb2(TeO4)(SO4) | triclinic | P1 | a=5.572, b=7.247, c=9.540, α=96.444° β=91.133° γ=110.222° Z=2 | 358.5 | [6] | |||
| Sb2(TeO3)2(SO4) | orthorhombic | Pbca | a=7.368, b=14.571, c=16.521, Z=8 | 1773.7 | [6] | |||
| Sb4O3(TeO3)2(HSO4)(OH) | monoclinic | C2/c | a=16.173 b=7.636 c=10.4138 β=92.257° | colourless | [7] | |||
| Ag2Ce(Te2O5)2SO4 | orthorhombic | Cmca | a =15.5581 b =10.7450 c =15.6309 | orange | [8] | |||
| Nd2Co(TeO3)2(SO4)2 | triclinic | P1 | [4] | |||||
| Nd2Cu(TeO3)2(SO4)2 | triclinic | P1 | light green | [5] | ||||
| Sm2Co(TeO3)2(SO4)2 | triclinic | P1 | [4] | |||||
| Sm2Cu(TeO3)2(SO4)2 | triclinic | P1 | light green | [5] | ||||
| Sm2Zn(TeO3)2(SO4)2 | triclinic | P1 | [4] | |||||
| Eu2Co(TeO3)2(SO4)2 | triclinic | P1 | [4] | |||||
| Eu2Cu(TeO3)2(SO4)2 | triclinic | P1 | light green | [5] | ||||
| Gd2Co(TeO3)2(SO4)2 | triclinic | P1 | [4] | |||||
| Gd2Zn(TeO3)2(SO4)2 | triclinic | P1 | [4] | |||||
| Tb2Cu(TeO3)2(SO4)2 | triclinic | P1 | light green | [5] | ||||
| Dy2Co(TeO3)2(SO4)2 | triclinic | P1 | [4] | |||||
| Dy2Cu(TeO3)2(SO4)2 | triclinic | P1 | light green | [5] | ||||
| Dy2Zn(TeO3)2(SO4)2 | triclinic | P1 | [4] | |||||
| Ho2Co(TeO3)2(SO4)2 | triclinic | P1 | [4] | |||||
| Ho2Cu(TeO3)2(SO4)2 | triclinic | P1 | light green | [5] | ||||
| Ho2Zn(TeO3)2(SO4)2 | triclinic | P1 | [4] | |||||
| Er2Co(TeO3)2(SO4)2 | triclinic | P1 | [4] | |||||
| Er2Cu(TeO3)2(SO4)2 | triclinic | P1 | light green | [5] | ||||
| Er2Zn(TeO3)2(SO4)2 | triclinic | P1 | [4] | |||||
| Tm2Cu(TeO3)2(SO4)2 | triclinic | P1 | light green | [5] | ||||
| Yb2Co(TeO3)2(SO4)2 | triclinic | P1 | [4] | |||||
| Yb2Cu(TeO3)2(SO4)2 | triclinic | P1 | light green | [5] | ||||
| Yb2Zn(TeO3)2(SO4)2 | triclinic | P1 | [4] | |||||
| Lu2Cu(TeO3)2(SO4)2 | triclinic | P1 | light green | [5] | ||||
| Hg3(Te3O8)(SO4) | 1208.64 | triclinic | P1 | a=6.4986 b=9.7848 c=10.713 alpha=67.178 beta=72.622 gamma=73.47 Z=2 | 588.10 | 6.825 | white | [3] |
| Bi2(TeO3)2(SO4) | monoclinic | C2/c | a = 15.766, b = 7.4285, c = 8.0959, β = 112.693°, Z = 4 | 874.7 | [9] | |||
| Ag2Th(Te2O5)2SO4 | orthorhombic | Cmca | a =15.679 b =10.8699 c =15.733 | colourless | [8] |
References
[edit]- ^ a b c Li, Peng-Fei; Hu, Chun-Li; Kong, Fang; Ying, Shao-Ming; Mao, Jiang-Gao (2021). "Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence". Inorganic Chemistry Frontiers. 8 (1): 164–172. doi:10.1039/D0QI01130D. ISSN 2052-1553.
- ^ Wang, Zhi-Cheng; Thanabalasingam, Kulatheepan; Scheifers, Jan P.; Streeter, Alenna; McCandless, Gregory T.; Gaudet, Jonathan; Brown, Craig M.; Segre, Carlo U.; Chan, Julia Y.; Tafti, Fazel (19 July 2021). "Antiferromagnetic Order and Spin-Canting Transition in the Corrugated Square Net Compound Cu 3 (TeO 4 )(SO 4 )·H 2 O". Inorganic Chemistry. 60 (14): 10565–10571. doi:10.1021/acs.inorgchem.1c01220.
- ^ a b c d Li, Peng-Fei; Hu, Chun-Li; Gong, Ya-Ping; Kong, Fang; Mao, Jiang-Gao (2021). "Hg 3 (Te 3 O 8 )(SO 4 ): a new sulfate tellurite with a novel structure and large birefringence explored from d 10 metal compounds". Chemical Communications. 57 (57): 7039–7042. doi:10.1039/D1CC02494A. ISSN 1359-7345.
- ^ a b c d e f g h i j k l m n o Lin, Jian; Diefenbach, Kariem; Silver, Mark A.; Dalal, Naresh S.; Albrecht-Schmitt, Thomas E. (2015-09-02). "Structure–Property Correlations in the Heterobimetallic 4f/3d Materials Ln 2 M(TeO 3 ) 2 (SO 4 ) (Ln = Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu; M = Co or Zn)". Crystal Growth & Design. 15 (9): 4606–4615. doi:10.1021/acs.cgd.5b00860. ISSN 1528-7483.
- ^ a b c d e f g h i j k Lin, Jian; Chai, Ping; Diefenbach, Kariem; Shatruk, Michael; Albrecht-Schmitt, Thomas E. (2014-03-25). "Challenges in the Search for Magnetic Coupling in 3d/4f Materials: Syntheses, Structures, and Magnetic Properties of the Lanthanide Copper Heterobimetallic Compounds, RE 2 Cu(TeO 3 ) 2 (SO 4 ) 2". Chemistry of Materials. 26 (6): 2187–2194. doi:10.1021/cm500252q. ISSN 0897-4756.
- ^ a b Zhang, Jiayuan; Zhao, Xiao; Wu, Yuandong; Mei, Dajiang; Wen, Shaoguo; Doert, Thomas (2021-06-25). "Synthesis, Crystal Structures, and Thermal Analyses of Two New Antimony Tellurite Sulfates: [Sb 2 (TeO 4 )](SO 4 ) and [Sb 2 (TeO 3 ) 2 ](SO 4 )". Zeitschrift für anorganische und allgemeine Chemie. 647 (12): 1269–1276. doi:10.1002/zaac.202100024. ISSN 0044-2313.
- ^ Li, Xiao-Fei; Wang, Kui; He, Chao; Li, Jin-Hua; An, Xing-Tao; Pan, Jie; Wei, Qi; Wang, Guo-Ming; Yang, Guo-Yu (2023-04-21). "Sb 4 O 3 (TeO 3 ) 2 (HSO 4 )(OH): An Antimony Tellurite Sulfate Exhibiting Large Optical Anisotropy Activated by Lone Pair Stereoactivity". Inorganic Chemistry: acs.inorgchem.3c00879. doi:10.1021/acs.inorgchem.3c00879. ISSN 0020-1669.
- ^ a b Poe, Todd N.; White, Frankie D.; Proust, Vanessa; Villa, Eric M.; Polinski, Matthew J. (2018-05-07). "[Ag 2 M(Te 2 O 5 ) 2 ]SO 4 (M = Ce IV or Th IV ): A New Purely Inorganic d/f-Heterometallic Cationic Material". Inorganic Chemistry. 57 (9): 4816–4819. doi:10.1021/acs.inorgchem.8b00504. ISSN 0020-1669.
- ^ Sun, Chuanling; Mei, Dajiang; Xu, Jingli; Wu, Yuandong (April 2017). "Hydrothermal synthesis, crystal structures, and optical properties of H[Bi3O(Te3O9)](NO3)2 and [Bi2(TeO3)2](SO4)". Journal of Alloys and Compounds. 702: 410–417. doi:10.1016/j.jallcom.2017.01.230.