User:Graeme Bartlett/indide
A indide is an inorganic chemical compound containing anions composed of indium atoms. Indium is right of the Zintl border in the periodic table, so indides are not Zintl compounds. They are a kind of intermetallic compound.
Related compounds include the thallides and gallides.
Indides contain clusters of indium atoms. There are compounds with 4, 5, 6, 8 11 atoms.[1] Four-atom clusters are tetrahedral and have interatomic distance of 3.171 Å, more dense than in indium metal.[2]
Production
[edit]Indides can be prepared by melting metals together under an inert atmosphere. For some combinations of metal, the boiling tmeperatuire of one may exceed the melting point of another, so the reaction is done in a sealed tantalum, niobium or molybdenum capsule.[3] An alternative is to use excess indium and crystallise from a molten indium flux.[3]
ref dump
[edit]more from intro of https://doi.org/10.1002/zaac.202300112 https://doi.org/10.1002/zaac.200700358 http://dx.doi.org/10.5012/bkcs.2013.34.6.1656 https://doi.org/10.1515/znb-2007-1214 The Gold-rich Indide Sr I Mutsa, UC Rodewaldb, Z Vasyl'I, R Pöttgenb https://doi.org/10.1021/ic2016275 https://doi.org/10.1021/ic701127f https://doi.org/10.1515/znb-2011-1003 https://doi.org/10.5012/bkcs.2013.34.12.3847 https://doi.org/10.1515/znb-2011-1104 https://doi.org/10.1021/ic8019765 https://link-springer-com.wikipedialibrary.idm.oclc.org/article/10.1134/S0020168523040106/tables/3 (melting points) https://iopscience.iop.org/article/10.1088/1674-1056/ac0a60/meta https://doi.org/10.1039/C4DT03783A https://doi.org/10.1515/zkri-2020-0012 https://doi.org/10.1016/j.intermet.2011.07.029 https://journals.aps.org/prb/abstract/10.1103/PhysRevB.107.174411 https://doi.org/10.1021/cg301532b https://link.springer.com/article/10.1007/s12039-013-0499-2 https://openurl.ebsco.com/EPDB%3Agcd%3A16%3A20871808/detailv2?sid=ebsco%3Aplink%3Ascholar&id=ebsco%3Agcd%3A93596039&crl=c https://doi.org/10.1021/ic401171v https://doi.org/10.1016/j.jallcom.2014.10.170 https://doi.org/10.1080/14786435.2015.1052859 https://doi.org/10.1515/zkri-2022-0024 https://doi.org/10.1515/znb-2011-0414 https://doi.org/10.1002/zaac.201600228 https://doi.org/10.1016/j.jssc.2015.10.032 review https://doi.org/10.1021/cg401864p https://doi.org/10.5560/znb.2014-4192 https://journals.jps.jp/doi/abs/10.7566/JPSJ.88.074702 https://iopscience.iop.org/article/10.1088/1742-6596/592/1/012047/meta https://journals.jps.jp/doi/abs/10.7566/JPSJ.86.084710 https://doi.org/10.1016/j.jallcom.2016.10.047 https://journals.jps.jp/doi/abs/10.7566/JPSCP.38.011099 https://iopscience.iop.org/article/10.1088/1742-6596/592/1/012007/meta https://arxiv.org/abs/1404.1660
List
[edit]formula | system | space group | unit cell | volume | density | comment | Reference |
---|---|---|---|---|---|---|---|
LiIn | [4][5] lots of referencs for these | ||||||
Li13In3 | [5] | ||||||
Li2In | [5] | ||||||
Li3In2 | [5] | ||||||
NaIn | [4] | ||||||
Na7KIn4 | Pbam | a=b=16.3283 c=11.3094 Z=8, | 3015.25 | [In4]8− tetrahedra | [1] | ||
Ca54In13B1.6H25.4 | cubic | Im3 | a = 16.3608 Z = 2 | 4376.7 | 2.768 | [6] | |
(Ca4N)[In2] | tetragonal | I41/amd | a = 4.9114 c = 29.077 | [7] | |||
(Ca7N4)[In] | a=11.68 b=12.13 c=3.64 | bronze colour | [8] | ||||
(Ca19N7)[In4]2 | cubic | a = 14.7165 | [7] | ||||
Ca8In2SiN4 | orthorhombic | Ibam | a = 12.904 b = 9.688 c = 10.899 Z = 4 | nitridosilicate | [9] | ||
ScNi4In | cubic | F43m | a=6.872 | [3] | |||
ScNi2In | cubic | Fm3m | a=6.256 | [3] | |||
Sc2Ni2In | tetragonal | P4/mbm | a=7.1679 c=3.33154 | [3] | |||
KCo2In9 | hexagonal | P6/mmm | a=8.7915 c=4.2364 | [10] | |||
KNi2In9 | hexagonal | P6/mmm | a=8.7915Å c=4.238 | [10] | |||
SrIn4 | [5] | ||||||
SrIn2 | [5] | ||||||
Sr3In11 | [5] | ||||||
SrIn | [5] | ||||||
Sr11In7 | [5] | ||||||
Sr5In3 | [5] | ||||||
Sr2.33In0.92 | [5] | ||||||
Sr6In4(In0.32Li0.92)N2.49 | cubic | a = 14.3752 Z=8 | 2959.4 | 4,744 | [11] | ||
(Sr19N7)[In4]2 | cubic | a = 15.610 | [7] | ||||
Li2Y5In9 | tetragonal | P4/nmm | a = 10.1242 c = 15.109 Z+4 | [12] | |||
YMnIn | hexagonal | P63/mmc | a=5.741 c=9.345 | [3] | |||
YNi9In2 | tetragonal | P4/mbm | a=8.222 c=4.827 | [3] | |||
YNi4In | cubic | F43m | a=7.034 | [3] | |||
YNiIn | hexagonal | P62m | a=7.486 c=3.784 | [3] | |||
YNiIn2 | Cmcm | a=4.314 b=10.406 c=7.276 | [3] | ||||
YNi1–0.50In1–1.50 | hexagonal | P62m | a=7.474–7.566 c=3.773–3.805 | [3] | |||
Y2Ni2In | orthorhombic | Cmmm | a=3.900 b=14.186 c=3.694 | [3] | |||
Y2Ni2-xIn | tetragonal | P4/mbm | a=7.365 c=3.679 | [3] | |||
Y12Ni6In | cubic | Im3 | a=9.711 | [3] | |||
Na8K23Cd12In48 | hexagonal | P6/mmm | [5] | ||||
BaIn4 | [5] | ||||||
BaIn2 | [5] | ||||||
BaIn | [5] | ||||||
Ba9In4 | [5] | ||||||
Ba9[In]4[H] | tetrahedral | I4/m | a = 13.973 c = 5.918 Z = 2 | [13] | |||
Ba6In4.78N2.72 | cubic | Fd3m | a=15.216 Z=8 | [11] | |||
(Ba6N)[In5] | trigonal | R3c | a = 8.234 c = 44.12 Z = 6 | 2590.6 | metallic grey | [14] | |
(Ba38N18)[In5]2[In8] | monoclinic | C2/m | a=57.334 b=7.9101 c=10.1991 β=97.237° Z=2 | [15] | |||
BaLi2.1In1.9 | hexagonal | P63/mmc | a=10.410 c=8.364 Z=6 | 785.0 | [5] | ||
BaLi1.12In0.98 | hexagonal | P6/mmm | a=17.469 c=10.6409 Z=30 | 2813.5 | [5] | ||
BaLi1.06In1.16 | rhombohedral | R3c | a=18.894 c=85.29 Z=276 | 26368 | [5] | ||
Li35In45Ba39N9 | tetragonal | I42m | a=15.299 c=30.682 Z=2 | 7182 | [5] | ||
LiIn2Ba3N0.83 | cubic | Fd3m | a=14.913 Z=8 | 3316.7 | [5] | ||
Ba11In6O3 | tetragonal | I4/mcm | a = 15.558 c = 11.216 Z = 4 | indide oxide | [16] | ||
LaNi7In6 | orthorhombic | Ibam | a=8.066 b=9.248 c=12.465 | [3] | |||
LaNi9In2 | tetragonal | P4/mbm | a=8.339 c=4.877 | [3] | |||
LaNi3In6 | orthorhombic | Pmmn | a=4.388 b=12.11 c=7.574 | [3] | |||
LaNi5In | hexagonal | P63/mmc | a=495.7 c=19.969 | [3] | |||
LaNi3In2 | hexagonal | P6/mmm | a=9.334 c=4.356 | [3] | |||
LaNiIn4 | orthorhombic | Cmcm | a=4.484 b=16.885 c=7.199 | [3] | |||
La4Ni7In8 | orthorhombic | Cmmm | a=14.757 b=24.187 c=4.398 | [3] | |||
La5Ni6In11 | orthorhombic | Cmmm | a=14.640 b=14.674 c=4.439 | [3] | |||
LaNi2In | orthorhombic | Pmma | a=5.254 b=4.131 c=7.169 | [3] | |||
LaNiIn | hexagonal | P62m | a=7.613 c=4.035 | [3] | |||
LaNi0.5In1.5 | hexagonal | P6/mmm | a=4.837 c=4.036 | [3] | |||
La2Ni2In | tetragonal | P4/mbm | a=7.611 c=3.918 | [3] | |||
La12Ni6In | cubic | Im3 | a=10.209 | [3] | |||
La4RuIn | cubic | F43m | a=14.241 Z=12 | 2888.4 | superconductor Tc=0.61K | [2][17] | |
CeCoIn5 | tetragonal | P4/mmm | a=4.601 c=7.540 | superconductor Tc=2.3 | [3][18] | ||
Ce2CoIn8 | tetragonal | P4/mmm | a=4.640 c=12.251 | [3] | |||
Ce4RuIn | cubic | F43m | a=13.963 Z=12 | 2722.5 | [2] | ||
Ce23Ru7In4 | hexagonal | P63mc | a = 9.861 c = 22.52 | melt congruently 683°С | [19] | ||
CeRhIn5 | [3] | ||||||
CeIrIn5 | [3] | ||||||
Pr6Fe13In | tetragonal | I4/mcm | a = 8.103 c = 2352.7 | [3] | |||
PrCoIn5 | tetragonal | P4/mmm | A=4.596 C=7.503 | [3] | |||
Pr2CoIn8 | tetragonal | P4/mmm | a=4.605 c=12.193 | [3] | |||
PrCo2In | orthorhombic | Pmma | a=5.119 B=4.089 c=7.197 | [3] | |||
Pr12Co6In | Im3 | a=9.920 | [3] | ||||
Pr4RuIn | cubic | F43m | a=13.999 Z=12 | 2743.4 | [2] | ||
Pr23Ru7In4 | hexagonal | P63mc | a = 9.9260 c = 22.4109 | melt incongruently 756°С | [19] | ||
Pr21Ru8.2In5 | tetragonal | I4/mcm | a=11.979 c=25.326 Z=4 | 3634.1 | 7.972 | [20] | |
NdMnIn | cubic | Fd3_m | a = 8.325 | [3] | |||
Nd6Fe13In | tetragonal | I4/mcm | a = 8.088 c = 23.431 | [3] | |||
NdCoIn5 | tetragonal | P4/mmm | a=4.590 c=7.502 | [3] | |||
Nd2CoIn8 | tetragonal | P4/mmm | a=4.608 c=12.172 | [3] | |||
NdCo2In | orthorhombic | Pmma | A=5.096 b=4.082 c=7.158 | [3] | |||
Nd12Co6In | Im3 | a=9.866 | [3] | ||||
Nd4RuIn | cubic | F43m | a=13.911 Z=12 | 2692.2 | [2] | ||
Nd26Ru8In9 | tetragonal | P4/mbm | a=12.1415 c=16.2303 Z=2 | 2392.6 | 7.762 | melt 812°С | [20] |
Sm6Fe13In | tetragonal | I4/mcm | a = 8.065 c = 23.202 | [3] | |||
SmCoIn5 | tetragonal | P4/mmm | a=4.577 c=7.463 | [3] | |||
Sm2CoIn8 | tetragonal | P4/mmm | a=4.583 c=12.101 | [3] | |||
SmCo2In | orthorhombic | Pmma | a=5.080 b=4.060 c=7.127 | [3] | |||
Sm2Co9In3 | orthorhombic | Cmmm | a=22.834 b=5.020 c=4.0842 | [3] | |||
Sm6Co2In | orthorhombic | Immm | a=9.549 b=9.583 c=10.068 | [3] | |||
Sm12Co6In | Im3 | a=9.786 | [3] | ||||
Sm4RuIn | cubic | F43m | a=13.809 Z=12 | 2633.1 | [2] | ||
GdMnIn | hexagonal | P63/mmc | a=5.778 c=9.412 | [3] | |||
GdCoIn5 | tetragonal | P4/mmm | a=4.567 c=7.461 | [3] | |||
Gd2CoIn8 | tetragonal | P4/mmm | a=4.569 c=12.021 | [3] | |||
GdCo2In | orthorhombic | Pmma | a=5.052 b=4.055 c=7.124 | [3] | |||
Gd6Co2In | orthorhombic | Immm | a=9.544 b=9.597 c=10.041 | [3] | |||
Gd14Co2In3 | tetragonal | P42/nmc | a=9.615 c=23.336 | [3] | |||
Gd23Co6.7In20.3 | orthorhombic | Pbam | a=23.59 b=28.89 c=3.628 | 2473 | [21] | ||
Gd4RhIn | cubic | F43m | a=13.707 Z=12 | 2575.3 | [2] | ||
Gd6Ru2In | orthorhombic | Immm | a=9.435 b=9.604 c=10.420 Z=4 | 944.2 | 8.867 | [20] | |
EuIn2 | [22] | ||||||
Eu3Co2In15 | tetragonal | P4/mbm | a = 14.789 c = 4.3945 | [10] | |||
Eu23Co6.7In20.3 | orthorhombic | Pbam | [21] | ||||
Eu3Cu2In9 | metallic | [23] | |||||
Eu3Rh2In15 | tetragonal | P4/mbm | a = 14.8346 c = 4.3970 Z=2 | 967.6 | 8.14 | [24] | |
EuAg4In8 | tetragonal | I4/mmm | a=9.7937 c=5.7492 | [25] | |||
Eu3Ag2In9 | orthorhombic | Immm | a = 4.8370 b = 10.6078 c = 13.9195 Z=2 | 714.21 | 7.928 | metallic | [23] |
TbCoIn5 | tetragonal | P4/mmm | a=4.549 c=7.425 | [3] | |||
Tb2CoIn8 | tetragonal | P4/mmm | a=4.568 c=12.008 | [3] | |||
TbCo2In | orthorhombic | Pmma | a=5.033 b=4.050 c=7.122 | [3] | |||
Tb6Co2.14In0.86 | orthorhombic | Immm | a=9.528 b=9.450 c=9.969 | [3] | |||
Tb14Co2In3 | tetragonal | P42/nmc | a=9.544 c=23.225 | [3] | |||
Tb23Co6.7In20.3 | orthorhombic | Pbam | a=23.448 b=28.722 c=3.5916 | 2418.9 | [21] | ||
Tb4RhIn | cubic | F43m | a=13.603 Z=12 | 2517.1 | [2] | ||
DyMnIn | hexagonal | P63/mmc | a=5.734 c=9.309 | [3] | |||
DyCoIn5 | tetragonal | P4/mmm | a=4.545 c=7.418 | [3] | |||
Dy2CoIn8 | tetragonal | P4/mmm | a=4.561 c=11.994 | [3] | |||
DyCo2In | orthorhombic | Pmma | a=4.998 b=4.034 c=7.060 | [3] | |||
Dy6Co2.14In0.86 | orthorhombic | Immm | a=9.401 b=9.438 c=9.938 | [3] | |||
Dy14Co2In3 | tetragonal | P42/nmc | a=9.500 c=23.002 | [3] | |||
DyCo4In | cubic | F43m | a=7.087 | [3] | |||
Dy3Co2In4 | hexagonal | P6 | a=7.867 c=3.645 | [3] | |||
Dy23Co6.7In20.3 | orthorhombic | Pbam | a=23.27 b=28.60 c=3.577 | 2380 | [21] | ||
Dy4RhIn | cubic | F43m | a=13.545 Z=12 | 2485.1 | [2] | ||
HoCoIn5 | tetragonal | P4/mmm | a=4.547 c=7.411 | [3] | |||
Ho2CoIn8 | tetragonal | P4/mmm | a=4.540 c=11.964 | [3] | |||
HoCo2In | orthorhombic | Pmma | a=4.993 b=4.029 c=7.054 | [3] | |||
Ho6Co2.14In0.86 | orthorhombic | Immm | a=9.348 b=9.430 c=9.906 | [3] | |||
Ho14Co2In3 | tetragonal | P42/nmc | a=9.459 c=22.913 | [3] | |||
HoCo4In | cubic | F43m | a=7.068 | [3] | |||
Ho3Co2In4 | hexagonal | P6 | a=7.866 c=3.605 | [3] | |||
Ho23Co6.7In20.3 | orthorhombic | Pbam | a=23.294 b=28.527 c=3.5468 | 2356.9 | [21] | ||
ErMnIn | hexagonal | P63/mmc | a=5.686 c=9.260 | [3] | |||
Er2CoIn8 | tetragonal | P4/mmm | a=4.560 c=11.958 | [3] | |||
Er14Co2In3 | tetragonal | P42/nmc | a=9.413 c=22.793 | [3] | |||
ErCo4In | cubic | F43m | a=7.049 | [3] | |||
Er3Co2In4 | hexagonal | P6 | a=7.850 c=3.583 | [3] | |||
Er6Co17.92In14 | Pm3 | a=8.663 | [3] | ||||
Er10Co9In20 | tetragonal | P4/mmm | a=13.253 c=9.078 | [3] | |||
Er23Co6.7In20.3 | orthorhombic | Pbam | a = 23.203 b = 28.399 c = 3.5306 Z=2 | 2326.5 | 9.383 | [21] | |
Er4RhIn | cubic | F43m | a=13.425 Z=12 | 2419.6 | [2] | ||
TmCoIn5 | tetragonal | P4/mmm | a=4.532 c=7.387 | [3] | |||
Tm2CoIn8 | tetragonal | P4/mmm | a=4.544 c=11.934 | [3] | |||
Tm6Co17.92In14 | Pm3 | a=8.655 | [3] | ||||
TmCo4In | cubic | F43m | a=7.042 | [3] | |||
Tm10Co9In20 | tetragonal | P4/mmm | a=13.166 c=9.097 | [3] | |||
Tm3Co2In4 | hexagonal | P6 | a=7.843 c=3.556 | [3] | |||
Tm6Co2.14In0.86 | orthorhombic | Immm | a=9.288 b=9.301 c=9.793 | [3] | |||
Tm14Co2In3 | tetragonal | P42/nmc | a=9.368 c=22.691 | [3] | |||
Tm23Co6.7In20.3 | orthorhombic | Pbam | a=23.141 b=28.328 c=3.5054 | 2297.8 | [21] | ||
Tm4RhIn | cubic | F43m | a=13.378 Z=12 | 2394.3 | [2] | ||
Yb~51In13H27 | cubic | Im3 | a = 16.218 Z = 2 | Yb54? | [26] | ||
YbCoIn5 | tetragonal | P4/mmm | a=4.5590 c=7.433 | [3] | |||
YbCu6In6 | tetragonal | I4/mmm | a = 9.220 c = 5.398 | [27] | |||
LuCoIn5 | tetragonal | P4/mmm | a=4.527 c=7.359 | [3] | |||
Lu6Co17.92In14 | Pm3 | a=8.652 | [3] | ||||
LuCo4In | cubic | F43m | a=7.029 | [3] | |||
Lu10Co9In20 | tetragonal | P4/mmm | a=13.160 c=9.106 | [3] | |||
Lu3Co2In4 | hexagonal | P6 | a=7.814 c=3.521 | [3] | |||
Lu6Co2.14In0.86 | orthorhombic | Immm | a=9.238 b=9.241 c=9.727 | [3] | |||
Lu14Co2In3 | tetragonal | P42/nmc | a=9.333 c=22.633 | [3] | |||
Lu23Co6.7In20.3 | orthorhombic | Pbam | a=22.950 b=28.05 c=3.488 | 2245 | [21] | ||
Lu37Ru16.4In4 | Ia3d | a = 27.562 | [28] | ||||
Lu4RhIn | cubic | F43m | a=13.297 Z=12 | 2351.1 | [2] | ||
IrIn2 | [29] | ||||||
IrIn3 | [29] | ||||||
Ir2In8S | tetragonal | P42/mnm | [30] | ||||
Sc1.024Ir2In0.976 | cubic | Fm3m | a = 639.97 | [31] | |||
Sc3Ir1.467In4 | hexagonal | P6 | a = 769.99 c = 684.71 | [31] | |||
Ir2In8Se | tetragonal | P42/mnm | a = 9.9200 c = 10.1092 Z=4 | 995.43 | 9.2213 | [30] | |
SrIrIn4 | [32] | ||||||
SrIr2In8 | orthorhombic | Pbam | a = 13.847 b = 16.113 c = 4.3962 | [33] | |||
SrIrIn6 | orthorhombic | Pmma | a = 8.5234 b = 4.3454 c = 10.5918 Z=2 | 392.3 | 8.20 | Ir@In9 tricapped trigonal prism+In@In8 cube | [29] |
SrIr9In18 | tetragonal | P4m2 | a = 8.1121 c = 8.5449 Z=1 | 562.3 | 11.47 | [32] | |
Ir2In8Te | tetragonal | P42/mnm | a = 10.005 c = 10.196 Z=4 | 1020.8 | 9.3091 | [30] | |
Y4IrIn | cubic | F43m | a=13.686 Z=12 | 2563.5 | [2] | ||
BaIrIn4 | orthorhombic | Pmma | a = 8.642 b = 4.396 c = 7.906 Z = 2 | [34] | |||
Ba2Ir4In13 | orthorhombic | Cmc21 | a = 4.4856 b = 29.052 c = 13.687 Z = 4 | [34] | |||
BaIr2In9 | hexagonal | P6/mmm | a = 8.8548 c = 4.2696 | thermal expansion c/a ~ 3 | [35] | ||
La4IrIn | cubic | F43m | a=14.372 Z=12 | 2968.3 | superconductor Tc=0.96K | [2][17] | |
La5Ir1.73In4.27 | orthorhombic | Pbam | a = 8.340 b = 18.622 c = 3.8531 | [36] | |||
Ce4IrIn | cubic | F43m | a=14.132 Z=12 | 2822.1 | [2] | ||
Pr4IrIn | cubic | F43m | a=14.044 Z=12 | 2770.1 | [2] | ||
Nd4IrIn | cubic | F43m | a=13.990 Z=12 | 2738.0 | [2] | ||
Nd39Ir10.98In36.02 | orthorhombic | Pbam | a = 31.754 b = 37.625 c = 3.7802 | 4516.4 | 8.73 | [37] | |
Sm4IrIn | cubic | F43m | a=13.859 Z=12 | 2661.7 | [2] | ||
Gd4IrIn | cubic | F43m | a=13.723 Z=12 | 2584.3 | [2] | ||
EuIrIn4 | orthorhombic | Pmma | a = 8.6065, b = 4.3033 c = 7.5765 | 280.6 | 9.51 | metallic grey; air stable | [22] |
EuIrIn4 | orthorhombic | Cmcm | a = 4.5206 b = 16.937 c = 7.266 Z=4 | 568.5 | 9.387 | metallic | [38] |
EuIr2In8 | orthorhombic | Pbam | a = 13.847 b = 16.118 c = 4.3885 | [33] | |||
Eu3Ir2In15 | tetragonal | P4/mbm | a = 14.8580 b = 14.8580 c = 4.3901 | [22][39] | |||
Tb4IrIn | cubic | F43m | a=13.653 Z=12 | 2545.0 | [2] | ||
Dy4IrIn | cubic | F43m | a=13.567 Z=12 | 2497.2 | [2] | ||
Ho4IrIn | cubic | F43m | a=13.539 Z=12 | 2481.9 | [2] | ||
Er4IrIn | cubic | F43m | a=13.441 Z=12 | 2428.3 | [2] | ||
Tm4IrIn | cubic | F43m | a = 13.4077 | [40] | |||
Lu20Ir5In3 | hexagonal | P62m | a=16.3058 c=9.2043 | 2074.8 | light grey; air stable | [41] | |
PtIn | [42] | ||||||
PtIn2 | a=6.353 | [43] | |||||
CaPtIn2 | orthorhombic | Cmcm | a = 4.463 b = 16.595, c = 7.568 | 560.5 | 8.23 | [44] | |
CaPtIn4 | orthorhombic | Cmcm | a = 4.463 b = 16.595 c = 7.568 | 560.5 | 8.23 | conchoidal fracture | [44] |
Sr4Pt10In21 | monoclinic | C2/m | a = 23.2262 b = 4.5027 c = 19.5809 β = 133.191° | 1493.0 | 10.50 | [45] | |
SrPt3In2 | orthorhombic | Imma | a = 16.747 b = 9.212 c = 9.712 | [46] | |||
Sr4In13Pt9 | orthorhombic | Pmmn | a = 4.3917 b = 12.322 c = 21.353 | [47] | |||
BaPtIn3 | [48] | ||||||
EuPtIn4 | orthorhombic | Cmcm | a=4.542 b=16.955 c=7.389 | [49] | |||
Eu5In9Pt7 | hexagonal | P6 | a = 11.167 c = 4.3586 | [47] | |||
Tb6Pt12In23 | monoclinic | C2/m | a = 28.346 b = 4.4005 c = 14.771 β = 112.37° | [50] | |||
Dy2Pt7In16 | orthorhombic | Cmmm | a = 12.111 b = 19.978 c = 4.3950 | [50] | |||
Lu4PtIn | cubic | F43m | a = 13.380 | [40] | |||
Lu20Pt5In3 | hexagonal | P62m | a=16.1853 c=9.1936 | 2120.1 | light grey; air stable | [41] | |
Lu26Pt7.55In9.45 | tetragonal | P4/mbm | a = 11.6532 c = 15.4746 Z=2 | [51] | |||
AuIn2 | a=6.502 | blue | [43][52] | ||||
Li2AuIn | greenish-yellow | [52] | |||||
K3Au5In | orthorhombic | Imma | a = 5.562 b = 19.645 c = 8.502 Z = 4 | [53] | |||
KAu4In2 | red-violet; water stable | [54][52] | |||||
RbAu4In2 | red-violet; water stable | [54][52] | |||||
Ca3Au3In | orthorhombic | Pnma | a = 16.641 b = 4.573 c = 8.950 | [55] | |||
SrAu1.1In2.9 | tetragonal | I4/mmm | a=4.5841 c=12.3725 Z=2 | [56] | |||
SrAu1.4Sn2.6 | tetragonal | I4/mmm | a=4.6447 c=11.403 Z=2 | 409.9 | 10.385 | [56] | |
SrAu3.36(2)In4.64 | monoclinic | P21/m | a=8.086 b=4.438 c=11.586 β=99.65° Z=2 | [52] | |||
Sr5Au13.5In8.5 | orthorhombic | Pnma | a= 4.7637 b=29.275 c= 8.949 | 1224.4 | 11.05 | [57] | |
SrAu2In2 | orthorhombic | Pnma | a = 8.530 b = 4.598 c = 12.283 Z = 4 | 482.00 | 9.801 | silvery | [58] |
SrAuIn3 | tetragonal | I4/mmm | a=4.5770 c=12.371 Z=2 | 259.16 | 8.024 | silvery | [58] |
SrAu4In4 | orthorhombic | Pnma | a = 13.946 b = 4.458 c = 12.921 Z = 4 | [59] | |||
Sr4Au9In13 | hexagonal | P6m2 | a = 12.701 c = 4.4350 Z = 1 | [59] | |||
BaAu2In2 | orthorhombic | Pnma | a = 8.755b = 4.712 c = 12.368 Z = 4 | 510.2 | 9.906 | silvery | [58] |
BaAuIn3 | tetragonal | I4/mmm | a = 4.8107 c = 11.980 Z=2 | 276.52 | 9.088 | [60] | |
EuAu2In4 | orthorhombic | Pnma | a = 18.5987 b = 4.6616 c = 7.4669 | [61] | |||
EuAuIn4 | orthorhombic | Cmcm | a = 4.6080 b = 17.0454 c = 7.5462 | [61] | |||
YbAu2In4 | monoclinic | P21/m | a = 7.654 b = 4.542 c = 9.591 β = 107.838° | [62] | |||
Yb2Au3In5 | orthorhombic | Cmc21 | a = 4.5351 b = 26.824 c = 7.464 | [62] | |||
Yb3AuGe2In3 | hexagonal | P62m | a = 7.3153 c = 4.4210 | [63] | |||
BaTl0.63In3.33 | [48] |
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(help) - ^ a b Tkachuk, Andriy V.; Mar, Arthur (2007-08). "Electron-poor SrAuxIn4−x (0.5⩽x⩽1.2) and SrAuxSn4−x (1.3⩽x⩽2.2) phases with the BaAl4-type structure". Journal of Solid State Chemistry. 180 (8): 2298–2304. doi:10.1016/j.jssc.2007.06.004.
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(help) - ^ Muts, Ihor; Rodewald, Ute Ch.; Zaremba, Vasyl’ I.; Pöttgen, Rainer (2011-11-01). "The Gold-rich Indide Sr 5 Au 13.5 In 8.5". Zeitschrift für Naturforschung B. 66 (11): 1101–1106. doi:10.1515/znb-2011-1104. ISSN 1865-7117.
- ^ a b c Dai, Jing-Cao; Corbett, John D. (2007-05-01). "Transformation of AeIn 4 Indides (Ae = Ba, Sr) into an AeAu 2 In 2 Structure Type Through Gold Substitution". Inorganic Chemistry. 46 (11): 4592–4598. doi:10.1021/ic070142v. ISSN 0020-1669.
- ^ a b Palasyuk, Andriy; Dai, Jing-Cao; Corbett, John D. (2008-04-01). "SrAu 4 In 4 and Sr 4 Au 9 In 13 : Polar Intermetallic Structures with Cations in Augmented Hexagonal Prismatic Environments". Inorganic Chemistry. 47 (8): 3128–3134. doi:10.1021/ic702145y. ISSN 0020-1669.
- ^ Liu, Shengfeng; Corbett, John D. (2004-08-01). "Synthesis, Structure, and Bonding of BaAuTl 3 and BaAuIn 3 : Stabilization of BaAl 4 -Type Examples of the Heavier Triels through Gold Substitution". Inorganic Chemistry. 43 (16): 4988–4993. doi:10.1021/ic040010r. ISSN 0020-1669.
- ^ a b Sarkar, Sumanta; Gutmann, Matthias J.; Peter, Sebastian C. (2013-10-02). "Crystal Structure and Magnetic Properties of Indium Flux Grown EuAu 2 In 4 and EuAuIn 4". Crystal Growth & Design. 13 (10): 4285–4294. doi:10.1021/cg400619p. ISSN 1528-7483.
- ^ a b Sebastian, C. Peter; Salvador, James; Martin, Joshua B.; Kanatzidis, Mercouri G. (2010-11-15). "New Intermetallics YbAu 2 In 4 and Yb 2 Au 3 In 5". Inorganic Chemistry. 49 (22): 10468–10474. doi:10.1021/ic101502e. ISSN 0020-1669.
- ^ Chondroudi, Maria; Peter, Sebastian C.; Malliakas, Christos D.; Balasubramanian, Mali; Li, Qing’An; Kanatzidis, Mercouri G. (2011-02-21). "Yb 3 AuGe 2 In 3 : An Ordered Variant of the YbAuIn Structure Exhibiting Mixed-Valent Yb Behavior". Inorganic Chemistry. 50 (4): 1184–1193. doi:10.1021/ic100975x. ISSN 0020-1669.