Tetrachloroethylene carbonate
Appearance
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Names | |
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IUPAC name
4,4,5,5-tetrachloro-1,3-dioxolan-2-one
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Other names
Perchloroethylene carbonate, tetrachloro-1,3-dioxolan-2-one
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Identifiers | |
3D model (JSmol)
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ChemSpider | |
EC Number |
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PubChem CID
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CompTox Dashboard (EPA)
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Properties | |
C3Cl4O3 | |
Molar mass | 225.83 g·mol−1 |
Density | 1.81[1] |
Hazards | |
GHS labelling:[2] | |
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Danger | |
H302, H314, H330 | |
P260, P264, P270, P271, P280, P284, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P320, P321, P330, P363, P403+P233, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Tetrachloroethylene carbonate is a carbonate ester with the chemical formula C2Cl4O2CO. It is produced by the photochlorination of ethylene carbonate. It has been used as precursor for oxalyl chloride.[3]
Tetrachloroethylene carbonate acts as a Lewis base and it forms a complex with the Lewis acid antimony pentachloride.[4] Tetrachloroethylene carbonate reacts with tributylamine, forming phosgene.[5]
See also
[edit]References
[edit]- ^ Yaws, C. L. (2015). The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals
- ^ "4,4,5,5-Tetrachloro-1,3-dioxolan-2-one". pubchem.ncbi.nlm.nih.gov.
- ^ Pfoertner, Karl-Heinz (2000). "Photochemistry". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a19_573. ISBN 3527306730.
- ^ Lewis Base Catalysis in Organic Synthesis. (2016). Wiley.
- ^ Pohanish, R. P., Greene, S. A. (2005). Wiley Guide to Chemical Incompatibilities. Wiley.