Jump to content

Template:Infobox niobium/sandbox

From Wikipedia, the free encyclopedia
Niobium, 00Nb
A lump of gray shining crystals with hexagonal facetting
Niobium
Pronunciation/nˈbiəm/ (ny-OH-bee-əm)
Appearancegray metallic, bluish when oxidized
Standard atomic weight Ar°(Nb)
Niobium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
V

Nb

Ta
zirconiumniobiummolybdenum
Groupgroup 5
Periodperiod 5
Block  d-block
Electron configuration[Kr] 4d4 5s1
Electrons per shell2, 8, 18, 12, 1
Physical properties
Phase at STPsolid
Melting point2750 K ​(2477 °C, ​4491 °F)
Boiling point5017 K ​(4744 °C, ​8571 °F)
Density (near r.t.)8.57 g/cm3
Heat of fusion30 kJ/mol
Heat of vaporization689.9 kJ/mol
Molar heat capacity24.60 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 2942 3207 3524 3910 4393 5013
Atomic properties
Oxidation statescommon: +5
−3,[3] −1,[4] 0,[5] +1,[5] +2,[4] +3,[4] +4[4]
ElectronegativityPauling scale: 1.6
Ionization energies
  • 1st: 652.1 kJ/mol
  • 2nd: 1380 kJ/mol
  • 3rd: 2416 kJ/mol
Atomic radiusempirical: 146 pm
Covalent radius164±6 pm
Color lines in a spectral range
Spectral lines of niobium
Other properties
Natural occurrenceprimordial
Crystal structurebody-centered cubic (bcc)
Cubic body-centered crystal structure for niobium
Thermal expansion7.3 µm/(m⋅K)
Thermal conductivity53.7 W/(m⋅K)
Electrical resistivity152 nΩ⋅m (at 0 °C)
Magnetic orderingparamagnetic
Young's modulus105 GPa
Shear modulus38 GPa
Bulk modulus170 GPa
Speed of sound thin rod3480 m/s (at 20 °C)
Poisson ratio0.40
Mohs hardness6.0
Vickers hardness1320 MPa
Brinell hardness736 MPa
CAS Number7440-03-1
History
Heinrich Rose (1844)
Isotopes of niobium
Main isotopes[6] Decay
abun­dance half-life (t1/2) mode pro­duct
91Nb synth 680 y β+ 91Zr
91mNb synth 60.86 d IT 91Nb
β+ 91Zr
92Nb trace 3.47×107 y β+ 92Zr
93Nb 100% stable
93mNb synth 16.12 y IT 93Nb
94Nb trace 2.04×104 y β 94Mo
95Nb synth 34.991 d β 95Mo
 Category: Niobium
| references

References

  1. ^ "Standard Atomic Weights: Niobium". CIAAW. 2017.
  2. ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  3. ^ Nb(–3) occurs in Cs3Nb(CO)5; see John E. Ellis (2003). "Metal Carbonyl Anions:  from [Fe(CO)4]2- to [Hf(CO)6]2- and Beyond†". Organometallics. 22 (17): 3322–3338. doi:10.1021/om030105l.
  4. ^ a b c d Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 28. ISBN 978-0-08-037941-8.
  5. ^ a b Nb(0) and Nb(I) has been observed in Nb(bpy)3 and CpNb(CO)4, respectively; see Holleman, Arnold F.; Wiberg, Egon; Wiberg, Nils (2008). Lehrbuch der Anorganischen Chemie (in German) (102 ed.). Walter de Gruyter. p. 1554. ISBN 9783110206845.
  6. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.