Talk:Acetic anhydride
This article is rated B-class on Wikipedia's content assessment scale. It is of interest to the following WikiProjects: | ||||||||||||||||||||||||
|
NFPA rating
[edit]List of NFPA 704 ratings shows code as 3-2-1, this page shows 2-2-1. Which is correct? --Ben Applegate 08:00, 24 August 2006 (UTC)
Reference
[edit]Industrielle organische Chemie: Bedeutende vor- und Zwischenprodukte SIDS Report might be good for the article.--Stone (talk) 08:38, 8 February 2008 (UTC)
Verify
[edit]Can someone please verify that the IUPAC nomenclature is acetic anhydride rather than ethanoic anhydride: I believe the latter is correct, but the former is placed on the article. Richard n 20:22, 10 February 2009 (UTC)
Acetic anhydride is right. See [1] and [2]. --Rifleman 82 (talk) 21:35, 10 February 2009 (UTC)
- PubChem says acetyl acetate. -Shootbamboo (talk) 13:50, 28 June 2009 (UTC)
Structure
[edit]So why not draw it with the carbonyls not facing each other then?
H3C H3C \ \ C==O C==O / / O instead use O \ \ C==O C--CH3 / // H3C O
Visually, this seems much more like what the charge distribution model graphic is appearing to show.
There is free rotation about both C-O bonds, and both methyl groups are equivalent by 1H NMR. Chemists like symmetry and this depiction seems more popular. --Rifleman 82 (talk) 02:33, 24 October 2011 (UTC)
Abbreviation or shorthand nonsense?
[edit]- When I was on the page for ethanoic acid, I read that it is „commonly“ abbreviated as Ac. I am not against the abbreviated of majuscule A & minuscule c [a very nice & convenient abbreviation if you ask me,] but accoding to scientific rules of chemical nomenclature, an abbreviation of a chemical shall only contain elements, not compounds.[1][2] There is even an interesting category of the naming of chemicals. Throughout my study of chemistry, I have never encountered exceptions to these rules [nor have I ever encountered the abbreviation of Ac, except only for the element 89. All I am asking if you can please provide with a reliable reference to your claim, say an updated book that includes & describes the abbreviation.
- Also, if it is not too much to ask can you also [anyone] fix the synonyms for the page Acetic anhydride. Ethyl_acetate, [though the chemical structure to acetic acid], is not the synonym for acetate anhydride. So, „Ethanoyl ethanoate“ is not the synonym for Acetate anhydride. As you can read by the chemical name itself, the suffix „-ide“ [being a single atom anion] is not the same as „-ate“ [being a polyatomic anion.] Then again, you can reference back to the derivative of acetic acid, acetate & argue the same. So, please: All I ask for everyone in Wikipedia is not to edit Wikipedia without assurance of reliable information, which means everyone needs to do their job to research before editing the page. Use the playground to carry out any mischievous experiments. Thank you.
- When I was on the page for ethanoic acid, I read that it is „commonly“ abbreviated as Ac. I am not against the abbreviated of majuscule A & minuscule c [a very nice & convenient abbreviation if you ask me,] but accoding to scientific rules of chemical nomenclature, an abbreviation of a chemical shall only contain elements, not compounds.[1][2] There is even an interesting category of the naming of chemicals. Throughout my study of chemistry, I have never encountered exceptions to these rules [nor have I ever encountered the abbreviation of Ac, except only for the element 89. All I am asking if you can please provide with a reliable reference to your claim, say an updated book that includes & describes the abbreviation.
- These are potentially useful suggestions and ideas. I think that most editors are pretty careful around the chemistry pages. The consensus seems to be that we not focus on formal nomenclature rules, which can distract from the otherwise very taxing problem of conveying the chemical concepts. People reading these pages are trying to understand bonds and routes, not abbreviations. We mainly use chemical formulas. I agree that Ac is not what I usually see (mainly OAc). --Smokefoot (talk) 20:26, 29 October 2011 (UTC)
References
Off-topic chat
[edit]Extended content
|
---|
ex-USSR Acetic anhydride was very popular among the junkies of ex-USSR for cooking heroin-like injectable drug from dry poppies, exactly like the ones sold in flower shops for $5 a poppy. A dose would take about 4-5 poppies so with that and time consumed on cooking and risks of bad or impure cook (a whole magic onto itself) - it makes more sense to just buy heroin from street drug dealers for $20 a dose--74.57.167.219 (talk) 01:08, 16 February 2015 (UTC)
|
Solubility?
[edit]https://pubchem.ncbi.nlm.nih.gov/compound/7918#section=Solubility
pubchem says 12 g/100ml, the article says 2.6
?? — Preceding unsigned comment added by 71.245.70.197 (talk) 18:28, 22 February 2015 (UTC)
External links modified
[edit]Hello fellow Wikipedians,
I have just modified 2 external links on Acetic anhydride. Please take a moment to review my edit. If you have any questions, or need the bot to ignore the links, or the page altogether, please visit this simple FaQ for additional information. I made the following changes:
- Added archive https://web.archive.org/web/20071011104749/http://www.bp.com/liveassets/bp_internet/globalbp/STAGING/global_assets/downloads/pdfs/acetyls_aromatics_pta/AceticAnhydrideFAQ.pdf to http://www.bp.com/liveassets/bp_internet/globalbp/STAGING/global_assets/downloads/pdfs/acetyls_aromatics_pta/AceticAnhydrideFAQ.pdf
- Added archive https://web.archive.org/web/20070927025258/http://www.celanese.com/msds/pdf/570-22027587.pdf to http://www.celanese.com/msds/pdf/570-22027587.pdf
When you have finished reviewing my changes, you may follow the instructions on the template below to fix any issues with the URLs.
This message was posted before February 2018. After February 2018, "External links modified" talk page sections are no longer generated or monitored by InternetArchiveBot. No special action is required regarding these talk page notices, other than regular verification using the archive tool instructions below. Editors have permission to delete these "External links modified" talk page sections if they want to de-clutter talk pages, but see the RfC before doing mass systematic removals. This message is updated dynamically through the template {{source check}}
(last update: 5 June 2024).
- If you have discovered URLs which were erroneously considered dead by the bot, you can report them with this tool.
- If you found an error with any archives or the URLs themselves, you can fix them with this tool.
Cheers.—InternetArchiveBot (Report bug) 23:50, 25 June 2017 (UTC)
Omission from "Structure and properties" section
[edit]At the end of the last paragraph in "Structure and properties" there is a parenthetical note saying "see electron density diagram." There is no electron density diagram anywhere on the article page and there is no direct link to another page that would have this information, not even a reference. I assume this was just an oversight, but if no diagram is forthcoming then perhaps this note should be removed. Lumberjane Lilly (talk) 17:00, 30 April 2021 (UTC)