Pinane
Appearance
Identifiers | |
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3D model (JSmol)
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1847301 | |
ChEBI | |
ChEMBL | |
ChemSpider | |
ECHA InfoCard | 100.006.790 |
EC Number |
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PubChem CID
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UNII |
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UN number | 3295 |
CompTox Dashboard (EPA)
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Properties | |
C10H18 | |
Molar mass | 138.254 g·mol−1 |
Appearance | colorless liquids |
Boiling point | 167.2 – 168 °C (cis) 164 °C (trans) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Pinane describes a pair of isomeric hydrocarbons. The isomers, actually diastereomers, are both chiral. They are the cis and trans isomers arising from the hydrogenation of the terpenes pinene. Both isomers undergo reaction with air (autoxidation) to give 2-pinane hydroperoxides.[1] Partial reduction of these isomers gives 2-pinanol.[2]
References
[edit]- ^ Erman, Mark B.; Kane, Bernard J. (2008). "Chemistry Around Pinene and Pinane: A Facile Synthesis of Cyclobutanes and Oxatricyclo-Derivative of Pinane from cis- and trans-Pinanols". Chemistry & Biodiversity. 5 (6): 910–919. doi:10.1002/cbdv.200890104. PMID 18618388. S2CID 24782774.
- ^ Eggersdorfer, Manfred (2000). "Terpenes". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a26_205. ISBN 3527306730.