Methyldioxirane
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| Names | |
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| IUPAC name
3-Methyldioxirane
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| Other names
Methyldioxirane
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
PubChem CID
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CompTox Dashboard (EPA)
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| Properties | |
| C2H4O2 | |
| Molar mass | 60.052 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Methyldioxirane is an organic chemical consisting of a methyl group as substituent on a dioxirane ring. It is a highly unstable structure that has been proposed as part of a decomposition reaction of acetaldehyde oxide, the Criegee intermediate during some ozonolysis reactions. The methyl group helps reduce the rate of ring-opening of the dioxirane, but it does not become usefully stable until a second substient is present as in the structure of dimethyldioxirane.[1][2]
References
[edit]- ^ Cremera, Dieter; Kraka, Elfi; G Szalay, Peter (1998). "Decomposition modes of dioxirane, methyldioxirane and dimethyldioxirane—a CCSD(T), MR-AQCC and DFT investigation". Chemical Physics Letters. 292 (1–2): 97–109. Bibcode:1998CPL...292...97C. doi:10.1016/S0009-2614(98)00678-2.
- ^ Selçuki, Cenk; Aviyente, Viktorya (2001). "Electrostatic solvent effects on the conversion of substituted carbonyl oxides to dioxiranes". Molecular Modeling Annual. 7 (4): 70–79. doi:10.1007/s008940100006. S2CID 91633921.
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