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Metallization pressure

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Metallization pressure is the pressure required for a non-metallic chemical element to become a metal. Every material is predicted to turn into a metal if the pressure is high enough, and temperature low enough. Some of these pressures are beyond the reach of diamond anvil cells, and are thus theoretical predictions. Neon has the highest metallization pressure for any element.

The value for phosphorus refers to pressurizing black phosphorus. The value for arsenic refers to pressurizing metastable black arsenic; grey arsenic, the standard state, is already a metallic conductor at standard conditions. No value is known or theoretically predicted for astatine and radon.

Z Element p, Mbar ref. type
1 Hydrogen 3.9 [1] theoretical
2 Helium 329 [2] theoretical
5 Boron 1.6 [3][4] experimental
6 Carbon 11 [5] theoretical
7 Nitrogen >> 5 [6] theoretical
8 Oxygen 0.96 [7][8] experimental
9 Fluorine 25 [9] theoretical
10 Neon 2084 [10] theoretical
14 Silicon 0.12 [11] experimental
15 Phosphorus 0.048 [12] experimental
16 Sulfur 0.83 [13] experimental
17 Chlorine 2.0 [14] experimental
18 Argon 5.1 [15] theoretical
32 Germanium 0.11 [16] experimental
33 Arsenic 0.022 [17] theoretical
34 Selenium 0.23 [18] experimental
35 Bromine 0.25 [19] experimental
36 Krypton 3.1 [15][20] theoretical
52 Tellurium 0.04 [21] experimental
53 Iodine 0.16 [22] experimental
54 Xenon 1.3 [23] experimental
85 Astatine . . .
86 Radon . . .

See also

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References

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  1. ^ McMinis, Jeremy; Clay, Raymond C.; Lee, Donghwa; Morales, Miguel A. (2015). "Molecular to Atomic Phase Transition in Hydrogen under High Pressure". Physical Review Letters. 114 (10): 105305. Bibcode:2015PhRvL.114j5305M. doi:10.1103/PhysRevLett.114.105305. PMID 25815944.
  2. ^ Monserrat, Bartomeu; Drummond, N. D.; Pickard, Chris J.; Needs, R. J. (2014). "Electron-Phonon Coupling and the Metallization of Solid Helium at Terapascal Pressures". Physical Review Letters. 112 (5): 055504. arXiv:1311.1005. Bibcode:2014PhRvL.112e5504M. doi:10.1103/PhysRevLett.112.055504. PMID 24580611. S2CID 29848984.
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  4. ^ Zhao, Jijun; Lu, Jian Ping (2002). "Pressure-induced metallization in solid boron". Physical Review B. 66 (9): 092101. arXiv:cond-mat/0109550. Bibcode:2002PhRvB..66i2101Z. doi:10.1103/PhysRevB.66.092101. S2CID 119426107.
  5. ^ Correa, Alfredo A.; Bonev, Stanimir A.; Galli, Giulia (2006). "Carbon under extreme conditions: phase boundaries and electronic properties from first-principles theory". Proceedings of the National Academy of Sciences of the United States of America. 103 (5): 1204–1208. Bibcode:2006PNAS..103.1204C. doi:10.1073/pnas.0510489103. ISSN 0027-8424. PMC 1345714. PMID 16432191.
  6. ^ Ma, Yanming; Oganov, Artem R.; Li, Zhenwei; Xie, Yu; Kotakoski, Jani (2009). "Novel High Pressure Structures of Polymeric Nitrogen". Physical Review Letters. 102 (6): 065501. Bibcode:2009PhRvL.102f5501M. doi:10.1103/PhysRevLett.102.065501. PMID 19257600.
  7. ^ Akahama, Yuichi; Kawamura, Haruki; Häusermann, Daniel; Hanfland, Michael; Shimomura, Osamu (June 1995). "New High-Pressure Structural Transition of Oxygen at 96 GPa Associated with Metallization in a Molecular Solid". Physical Review Letters. 74 (23): 4690–4694. Bibcode:1995PhRvL..74.4690A. doi:10.1103/PhysRevLett.74.4690. PMID 10058574.
  8. ^ Elatresh, Sabri F.; Bonev, Stanimir A. (2020). "Stability and metallization of solid oxygen at high pressure". Physical Chemistry Chemical Physics. 22 (22): 12577–12583. Bibcode:2020PCCP...2212577E. doi:10.1039/C9CP05267D. OSTI 1860780. PMID 32452471. S2CID 218891958.
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  10. ^ Tang, Jun; Ao, Bingyun; Huang, Li; Ye, Xiaoqiu; Gu, Yunjun; Chen, Qifeng (2019). "Metallization and positive pressure dependency of bandgap in solid neon". The Journal of Chemical Physics. 150 (11): 111103. Bibcode:2019JChPh.150k1103T. doi:10.1063/1.5089489. PMID 30901987.
  11. ^ Hu, Jing Zhu; Merkle, Larry D.; Menoni, Carmen S.; Spain, Ian L. (1986). "Crystal data for high-pressure phases of silicon". Physical Review B. 34 (7): 4679–4684. Bibcode:1986PhRvB..34.4679H. doi:10.1103/PhysRevB.34.4679. hdl:10217/634. PMID 9940261.
  12. ^ Okajima, Michio; Endo, Shoichi; Akahama, Yuichi; Narita, Shin-ichiro (1984). "Electrical Investigation of Phase Transition in Black Phosphorus under High Pressure". Japanese Journal of Applied Physics. 23 (1): 15–19. Bibcode:1984JaJAP..23...15O. doi:10.1143/JJAP.23.15. S2CID 121615032.
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  16. ^ Vohra, Yogesh K.; Brister, Keith E.; Desgreniers, Serge; Ruoff, Arthur L.; Chang, K. J.; Cohen, Marvin L. (1986). "Phase-Transition Studies of Germanium to 1.25 Mbar". Physical Review Letters. 56 (18): 1944–1947. Bibcode:1986PhRvL..56.1944V. doi:10.1103/PhysRevLett.56.1944. PMID 10032817.
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  21. ^ Marini, C.; Chermisi, D.; Lavagnini, M.; Di Castro, D.; Petrillo, C.; Degiorgi, L.; Scandolo, S.; Postorino, P. (2012). "High-pressure phases of crystalline tellurium: A combined Raman and ab initio study". Physical Review B. 86 (6): 064103. Bibcode:2012PhRvB..86f4103M. doi:10.1103/PhysRevB.86.064103.
  22. ^ Pasternak, M.; Farrell, J. N.; Taylor, R. D. (1987). "Metallization and structural transformation of iodine under pressure: A microscopic view". Physical Review Letters. 58 (6): 575–578. Bibcode:1987PhRvL..58..575P. doi:10.1103/physrevlett.58.575. PMID 10034976.
  23. ^ Eremets, Mikhail; Gregoryanz, Eugene; Struzhkin, Victor; Mao, Ho-Kwang; Hemley, Russell; Mulders, Norbert; Zimmerman, Neil (2000). "Electrical Conductivity of Xenon at Megabar Pressures". Physical Review Letters. 85 (13): 2797–2800. Bibcode:2000PhRvL..85.2797E. doi:10.1103/PhysRevLett.85.2797. PMID 10991236.
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