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Neodymium nickelate is the name given to four nickelates of neodymium with the chemical formulae of NdNiO3, NdNiO2, Nd2NiO4 and Nd4Ni3O8.
NdNiO3
[edit]| Names | |
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| Other names
Neodymium(III) nickelate
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| Identifiers | |
3D model (JSmol)
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| Properties | |
| NdNiO3 | |
| Molar mass | 250.932 g·mol−1 |
| Hazards | |
| GHS labelling:[1] | |
 
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| Danger | |
| H317, H350, H372 | |
| P261, P263, P280, P405, P501 | |
| Related compounds | |
Other anions
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Neodymium(III) oxide Neodymium(III) acetate Neodymium(III) hydride |
Other cations
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europium nickelate lanthanum nickelate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Preparation
[edit]Nd2NiO3 can be prepared by dissolving neodymium(III) oxide and nickel(II) oxide in nitric acid, followed by heating the mixture in an oxygen atmosphere.[2]
It can also be prepared by pyrolyzing a mixture of nickel nitrate and neodymium nitrate.[2][3]
It decomposes in high temperature (950 °C) by nitrogen:[2]
- 4 NdNiO3 → 2 Nd2NiO4 + 2 NiO + O2
It can also be reduced to the monovalent nickel compound NdNiO2 by sodium hydride at 160°C.[4]
Physical properties
[edit]Neodymium nickelate shows metal-insulator transition (MIT) under low temperature.[5][6] The temperature at which it transforms (TMIT) is 400K,[7] which is higher than praseodymium nickelate (200K) but lower than samarium nickelate (460K).[5][7][8] It transforms from antiferromagnetism to paramagnetism. It has demonstrated to be a first-order phase transition (this applies for praseodymium nickelate as well).[5] The temperature (TN) can be changed by varying the NiO6 octahedral distortion.[5][6] It is the only lathanide nickelate to have the same TMIT as TN.[5]
Uses
[edit]In a 2010 study, it was found that neodymium nickelate as an anode material provided 1.7 times the current density of typical LSM anodes when integrated into a commercial SOEC and operated at 700 °C, and approximately 4 times the current density when operated at 800 °C. The increased performance is postulated to be due to higher "overstoichiometry" of oxygen in the neodymium nickelate, making it a successful conductor of both ions and electrons.[9]
Neodymium nickelate can also be used in electrocatalysts, synapse transistors, photovoltaics, memory resistors, biosensors, and electric-field sensors.[5]
References
[edit]- ^ "Safety Data Sheet Neodymium Nickel Oxide" (PDF). LTS Research Laboratories, Inc. 13 July 2015. Retrieved 26 March 2022.
- ^ a b c Vassiliou, John K.; Hornbostel, Marc; Ziebarth, Robin; Disalvo, F.J. (1989). "Synthesis and properties of NdNiO3 prepared by low-temperature methods". Journal of Solid State Chemistry. 81 (2). Elsevier BV: 208–216. Bibcode:1989JSSCh..81..208V. doi:10.1016/0022-4596(89)90008-x. ISSN 0022-4596.
- ^ M.T. Escote, A.M.L. da Silva, J.R. Matos, R.F. Jardim (May 2000). "General Properties of Polycrystalline LnNiO3 (Ln=Pr, Nd, Sm) Compounds Prepared through Different Precursors". Journal of Solid State Chemistry. 151 (2): 298–307. Bibcode:2000JSSCh.151..298E. doi:10.1006/jssc.2000.8657. Retrieved 2022-03-18.
{{cite journal}}: CS1 maint: multiple names: authors list (link) - ^ M.A. Hayward, M.J. Rosseinsky (June 2003). "Synthesis of the infinite layer Ni(I) phase NdNiO2+x by low temperature reduction of NdNiO3 with sodium hydride". Solid State Sciences. 5 (6): 839–850. Bibcode:2003SSSci...5..839H. doi:10.1016/S1293-2558(03)00111-0. Retrieved 2022-03-18.
- ^ a b c d e f Yang, Hongwei; Wen, Zhiwei; Shu, Jun; Cui, Yajing; Chen, Yongliang; Zhao, Yong (2021). "Structural, electrical, and magnetic properties of bulk Nd1-Sr NiO3 (x = 0–0.3)". Solid State Communications. 336. Elsevier BV: 114420. doi:10.1016/j.ssc.2021.114420. ISSN 0038-1098.
- ^ a b Subir Roy, Rajesh Katoch, R.B. Gangineni, S. Angappane, Investigation of metal-insulator transition temperature and magnetic properties of NdNiO3 nanoparticles, Journal of Solid State Chemistry, Volume 294, 2021, 121865, ISSN 0022-4596, https://doi.org/10.1016/j.jssc.2020.121865.
- ^ a b Lafez, P.; Ruello, P.; Edely, M. (2008). "Electrical and Infrared Properties of RF Sputtering of Rare Earth Nickelate (RNiO3) Thin Films with Metal Insulator-Transitions". In Lamont, Paul W. (ed.). Leading-Edge Materials Science Research. Nova Publishers. pp. 277–310. ISBN 9781600217982. Retrieved 21 April 2016.
- ^ Jorgensen, Finn. The Complete Handbook of Magnetic Recording; McGraw-Hill, 1996.
- ^ Chauveau, F.; Mougin, J.; Bassat, J.M.; Mauvy, F.; Grenier, J.C. (2010). "A new anode material for solid oxide electrolyser: The neodymium nickelate Nd2NiO4+δ". Journal of Power Sources. 195 (3). Elsevier BV: 744–749. doi:10.1016/j.jpowsour.2009.08.003. ISSN 0378-7753.