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An oxyhydride is a mixed anion compound containing both oxide O2− and hydride ions H−. These compounds may be unexpected as the hydrogen and oxygen could be expected to react to form water. But if the metals making up the cations are electropositive enough, and the conditions are reducing enough, solid materials can be made that combine hydrogen and oxygen in the negative ion role.[1]

Production

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The first oxyhydride to be discovered was lanthanum oxyhydride, a 1982 discovery. It was made by heating lanthanum oxide in an atmosphere of hydrogen at 900 °C.[2] However, heating transition metal oxides with hydrogen usually results in water and the reduced metal.[2]

Topochemical synthesis retains the basic structure of the parent compound, and only does the minimum rearrangements of atoms to convert to the final product.[2] Topotactic transitions retain the original crystal symmetry.[2] Reactions at lower temperatures do not distort the existing structure. Oxyhydrides in a topochemical synthesis can be produced by heating oxides with sodium hydride NaH or calcium hydride CaH2 at temperatures from 200–600 °C.[3] TiH2 or LiH can also be used as an agent to introduce hydride.[2] If calcium hydroxide or sodium hydroxide is formed, it might be able to be washed away.[2] However for some starting oxides, this kind of hydride reduction might just yield an oxygen-deficient oxide.[2]

Reactions under hot high-pressure hydrogen can result from heating hydrides with oxides. A suitable seal for the lid on the container is required, and one such substance is sodium chloride.[4]

Oxyhydrides all contain an alkali metal, alkaline earth metal, or rare-earth element, which are needed in order to put electronic charge on hydrogen.[4]

Properties

[edit]

The hydrogen bonding in oxyhydrides can be covalent, metallic, and ionic bonding, depending on the metals present in the compound.[4]

Oxyhydrides lose their hydrogen less than the pure metal hydrides.[3]

The hydrogen in oxyhydrides is much more exchangeable. For example oxynitrides can be made at much lower temperatures by heating the oxyhydride in ammonia or nitrogen gas (say around 400 °C rather than 900 °C required for an oxide)[3] Acidic attack can replace the hydrogen, for example moderate heating in hydrogen fluoride yields compounds containing oxide, fluoride, and hydride ions (oxyfluorohydride.[5]) The hydrogen is more thermolabile, and can be lost by heating yielding a reduced valence metal compound.[3]

Changing the ratio of hydrogen and oxygen can modify electrical or magnetic properties. Then band gap can be altered.[3] The hydride atom can be mobile in a compound undergoing electron coupled hydride transfer.[4] The hydride ion is highly polarisable, so it presence raised the dielectric constant and refractive index.[4]

Some oxyhydrides have photocatalytic capability. For example BaTiO2.5H0.5 can function as a catalyst for ammonia production from hydrogen and nitrogen.[3]

The hydride ion is quite variable in size, ranging from 130 to 153 pm.[4]

The hydride ion actually does not only have a −1 charge, but will have a charge dependent on its environment, so it is often written as Hδ−.[4] In oxyhydrides, the hydride ion is much more compressible than the other atoms in compounds.[4] Hydride is the only anion with no π orbital, so if it is incorporated into a compound, it acts as a π-blocker, reducing dimensionality of the solid.[4]

Oxyhydride structures with heavy metals cannot be properly studied with X-ray diffraction, as hydrogen hardly has any effect on X-rays. Neutron diffraction can be used to observe hydrogen, but not if there are heavy neutron absorbers like Eu, Sm, Gd, Dy in the material.[2]

List

[edit]
Formula Structure Space group Unit cell Volume Density Comments Reference
Na3SO4H tetrahedral P4/nmm a=7.0034 c=4.8569 [6]
[η1-3,5-tBu2pz(η-Al)H)2O]2 pz=pyrazolato triclinic P1 a=10.202 b=13.128 c=13.612 α=112.39 β=101.90 γ=96.936 Z=1 1608.7 1.162 [7]
(MeLAlH)2(μ-O)

MeL = HC[(CMe)N(2,4,6-Me3C6H2)]2–

white [8][9]
CaTiO3−xHx (x ≤ 0.6) Conducting; H in disordered position [3]
Mg2AlNiXHZOY [10]
Sr2LiH3O ionic conductor [11]
Sr3AlO4H tetragonal I4/mcm a =6.7560 c =11.1568 [12]
Sr2CaAlO4H tetragonal I4/mcm a= 6.6220 c= 10.9812 481.531 [12]
Sr21Si2O5H14 cubic [13]
Sr5(BO3)3H orthorhombic Pnma a=7.1982, b=14.1461, c=9.8215 1000.10 decomposed by water [14]
LiSr2SiO4H monoclinic P21/m a = 6.5863, b = 5.4236, c = 6.9501, β = 112.5637 air stable [15]
Sr21Si2O5H12+x cubic Fd3m a = 19.1190 [16]
Sr5(PO4)3H hexagonal P63/m a = 9.7169, c = 7.2747 594.83 for deuteride [17]
SrTiO3−xHx (x ≤ 0.6) Conducting; H in disordered position [3]
SrVO2H [3]
Sr2VO3H [3]
Sr3V2O5H2 [3]
SrCrO2H cubic produced under 5GPa 1000 °C [3]
Sr3Co2O4.33H0.84 insulator [3]
YHO orthorhombic Pnma a = 7.5367, b = 3.7578, c = 5.3249 [18]
YOxHy photochromic; band gap 2.6 eV [19]
Zr3V3OD5 [2]
Zr5Al3OH5 [2]
Ba3AlO4H orthorhombic Pnma Z=4,a=10.4911,b=8.1518,c=7.2399 [20]
BaTiO3−xHx (x ≤ 0.6) Conducting; H in disordered position [3]
Ba2NaTiO3H3 cubic Fm3m a=8.29714 [21]
BaVO3−xHx (x = .3) 5 GPa hexagonal, 7GPa cubic [3]
Ba2NaVO2.4H3.6 cubic Fm3m a=8.22670 [21]
BaCrO2H hexagonal P63/mmc a =5.6559 c =13.7707 [22]
Ba2NaCrO2.2H3.8 cubic Fm3m a=8.17470 [21]
Ba21Zn2O5H12 cubic Fd3m a = 20.417 [13]
Sr2BaAlO4H tetragonal I4/mcm a =6.9093 c =11.2107 [12]
Ba21Cd2O5H12 cubic Fd3m a=20.633 [13]
Ba21Hg2O5H12 cubic Fd3m a=20.507 [13]
Ba21In2O5H12 cubic Fd3m a=20.607 [13]
Ba21Tl2O5H12 cubic Fd3m a=20.68 [13]
Ba21Si2O5H14 cubic Fd3m a=20.336 [13]
Ba21Ge2O5H14 cubic Fd3m a=20.356 [13]
Ba21Sn2O5H14 cubic Fd3m a=20.532 [13]
Ba21Pb2O5H14 cubic Fd3m a=20.597 [13]
Ba21As2O5H16 cubic Fd3m a=20.230 [13]
Ba21Sb2O5H16 cubic Fd3m a=20.419 [13]
BaScO2H Cubic Pm3̅m a=4.1518 [23]
Ba2ScHO3 H− conductor [24]
Ba2YHO3 a=4.38035 c=13.8234 H− conductor [25]
Ba3AlO4H [2]
Ba21Si2O5H24 cubic Fd3m a = 20.336 Zintl phase [2]
Ba21Zn2O5H24 cubic Fd3m a = 20.417 [26]
Ba21Ge2O5H24 cubic Fd3m a = 20.356 Zintl phase [2]
Ba21Ga2O5H24 cubic Fd3m Zintl phase [2]
Ba21As2O5H24 cubic Fd3m a = 20.230 [26]
Ba21Cd2O5H24 cubic Fd3m a = 20.633 [26]
Ba21In2O5H24 cubic Fd3m a = 20.607 Zintl phase [2]
Ba21Sn2O5H24 cubic Fd3m a = 20.532 [26]
Ba21Sb2O5H24 cubic Fd3m a = 20.419 [26]
La2LiHO3 orthorhombic Immm a=3.57152 b=3.76353 c=12.9785 [4][27]
La0.6Sr1.4LiH1.6O2 H− conductor [4]
LaSr3NiRuO4H4 [3]
LaSrMnO3.3H0.7 high-pressure fabrication [3]
LaSrCoO3H0.7 insulator [3]
Nd0.8Sr0.2NiO2Hx (x = 0.2–0.5) superconductor for x between 0.22 and 0.28 [28]
EuTiO3−xHx (x ≤ 0.6) Conducting; H in disordered position [3]
LiEu2HOCl2 orthorhombic Cmcm a = 14.923, b = 5.7012, c = 11.4371, Z = 8 density 5.444; yellow [29]
LaHO [30]
CeHO [30]
PrHO [30]
NdHO P4/nmm a=7.8480, c=5.5601 V=342.46 [30]
GdHO Fmm a = 5.38450 [31]
HoHO F4̅3m a = 5.2755 light-yellow under the sun; pink indoors [32]
DyHO cubic F4̅3m a=5.3095 [33]
ErHO cubic F4̅3m a=5.24615 [33]
LuHO cubic F4̅3m a=5.17159 [33]
LuHO orthorhombic Pnma a = 7.3493, b = 3.6747, c = 5.1985 [33]
CeNiHZOY Catalyse ethanol to H2 [34]
Ba21Tl2O5H24 cubic Fd3m a = 20.68 Zintl phase [2]
Ba21Hg2O5H24 cubic Fd3m a = 20.507 [26]
Ba21Pb2O5H24 cubic Fd3m a = 20.597 [26]
Ba21Bi2O5H16 cubic Fd3m a=20.459 [13]
PuHO Formed during corrosion of plutonium metal in water [35]

Three or more anions

[edit]
Formula Structure Space group Unit cell Comments Reference
LiEu2HOCl2 orthorhombic Cmcm a = 14.923 b = 5.7012 c = 11.4371 Z = 8 yellow [36]
Sr2LiHOCl2 orthorhombic Cmcm a = 15.0235 b = 5.69899 c = 11.4501 synthesized at ambient pressure and 2 GPa; ordered H/O [37]
Sr2LiHOCl2 tetragonal I4/mmm a = 4.04215 c = 15.04359 synthesized at 5 GPa; disordered H/O [37]
Sr2LiHOBr2 tetragonal I4/mmm a = 4.1097 c = 16.1864 synthesized at 5 GPa; disordered H/O [37]
Ba2LiHOCl2 tetragonal I4/mmm a = 4.26816 c = 15.6877 synthesized at 5 GPa; disordered H/O [37]

See also

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References

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  1. ^ Wang, Kristen; Wu, Zili; Jiang, De-en (2022). "Ammonia synthesis on BaTiO 2.5 H 0.5 : computational insights into the role of hydrides". Physical Chemistry Chemical Physics. 24 (3): 1496–1502. Bibcode:2022PCCP...24.1496W. doi:10.1039/D1CP05055A. OSTI 1881073. PMID 34935803.
  2. ^ a b c d e f g h i j k l m n o p Kobayashi, Yoji; Hernandez, Olivier; Tassel, Cédric; Kageyama, Hiroshi (16 November 2017). "New chemistry of transition metal oxyhydrides". Science and Technology of Advanced Materials. 18 (1): 905–918. Bibcode:2017STAdM..18..905K. doi:10.1080/14686996.2017.1394776. PMC 5784496. PMID 29383042.
  3. ^ a b c d e f g h i j k l m n o p q r s Kageyama, Hiroshi; Yajima, Takeshi; Tsujimoto, Yoshihiro; Yamamoto, Takafumi; Tassel, Cedric; Kobayashi, Yoji (15 August 2019). "Exploring Structures and Properties through Anion Chemistry". Bulletin of the Chemical Society of Japan. 92 (8): 1349–1357. doi:10.1246/bcsj.20190095.
  4. ^ a b c d e f g h i j k Kageyama, Hiroshi; Hayashi, Katsuro; Maeda, Kazuhiko; Attfield, J. Paul; Hiroi, Zenji; Rondinelli, James M.; Poeppelmeier, Kenneth R. (22 February 2018). "Expanding frontiers in materials chemistry and physics with multiple anions". Nature Communications. 9 (1): 772. Bibcode:2018NatCo...9..772K. doi:10.1038/s41467-018-02838-4. PMC 5823932. PMID 29472526.
  5. ^ KAMIGAITO, Osami (2000). "Density of Compound Oxides". Journal of the Ceramic Society of Japan. 108 (1262): 944–947. doi:10.2109/jcersj.108.1262_944.
  6. ^ Mutschke, Alexander; Bernard, Guy M.; Bertmer, Marko; Karttunen, Antti J.; Ritter, Clemens; Michaelis, Vladimir K.; Kunkel, Nathalie (2021-03-08). "Na 3 SO 4 H—The First Representative of the Material Class of Sulfate Hydrides". Angewandte Chemie International Edition. 60 (11): 5683–5687. doi:10.1002/anie.202016582. ISSN 1433-7851. PMC 7986708. PMID 33438295.
  7. ^ Zheng, Wenjun; Mösch-Zanetti, Nadia C.; Roesky, Herbert W.; Noltemeyer, Mathias; Hewitt, Manuel; Schmidt, Hans-Georg; Schneider, Thomas R. (2000-12-01). "Alumoxane Hydride and Aluminum Chalcogenide Hydride Compounds with Pyrazolato Ligands". Angewandte Chemie (in German). 112 (23): 4446–4449. Bibcode:2000AngCh.112.4446Z. doi:10.1002/1521-3757(20001201)112:23<4446::AID-ANGE4446>3.0.CO;2-I.
  8. ^ González-Gallardo, Sandra; Cruz-Zavala, Aracely S.; Jancik, Vojtech; Cortés-Guzmán, Fernando; Moya-Cabrera, Mónica (2013-03-18). "Preparation of Telluro- and Selenoalumoxanes under Mild Conditions". Inorganic Chemistry. 52 (6): 2793–2795. doi:10.1021/ic302588f. ISSN 0020-1669. PMID 23458274.
  9. ^ González-Gallardo, Sandra; Jancik, Vojtech; Cea-Olivares, Raymundo; Toscano, Rubén A.; Moya-Cabrera, Mónica (2007-04-13). "Preparation of Molecular Alumoxane Hydrides, Hydroxides, and Hydrogensulfides". Angewandte Chemie International Edition. 46 (16): 2895–2898. doi:10.1002/anie.200605081. ISSN 1433-7851. PMID 17373011.
  10. ^ Fang, Wenhao; Romani, Yann; Wei, Yaqian; Jiménez-Ruiz, Mónica; Jobic, Hervé; Paul, Sébastien; Jalowiecki-Duhamel, Louise (September 2018). "Steam reforming and oxidative steam reforming for hydrogen production from bioethanol over Mg2AlNiXHZOY nano-oxyhydride catalysts" (PDF). International Journal of Hydrogen Energy. 43 (37): 17643–17655. doi:10.1016/j.ijhydene.2018.07.103. S2CID 105746959.
  11. ^ Kobayashi, G.; Hinuma, Y.; Matsuoka, S.; Watanabe, A.; Iqbal, M.; Hirayama, M.; Yonemura, M.; Kamiyama, T.; Tanaka, I.; Kanno, R. (17 March 2016). "Pure H- conduction in oxyhydrides". Science. 351 (6279): 1314–1317. Bibcode:2016Sci...351.1314K. doi:10.1126/science.aac9185. PMID 26989251.
  12. ^ a b c Wu, Tong; Fujii, Kotaro; Murakami, Taito; Yashima, Masatomo; Matsuishi, Satoru (2020-10-19). "Synthesis and Photoluminescence Properties of Rare-Earth-Activated Sr 3– x A x AlO 4 H (A = Ca, Ba; x = 0, 1): New Members of Aluminate Oxyhydrides". Inorganic Chemistry. 59 (20): 15384–15393. doi:10.1021/acs.inorgchem.0c02356. ISSN 0020-1669. PMID 32991153. S2CID 222146038.
  13. ^ a b c d e f g h i j k l m Jehle, Michael; Hoffmann, Anke; Kohlmann, Holger; Scherer, Harald; Röhr, Caroline (February 2015). "The 'sub' metallide oxide hydrides Sr 21 Si 2 O 5 H 12 + x and Ba 21 M 2 O 5 H 12 + x (M = Zn, Cd, Hg, In, Tl, Si, Ge, Sn, Pb, As, Sb, Bi)". Journal of Alloys and Compounds. 623: 164–177. doi:10.1016/j.jallcom.2014.09.228.
  14. ^ Wylezich, Thomas; Valois, Renaud; Suta, Markus; Mutschke, Alexander; Ritter, Clemens; Meijerink, Andries; Karttunen, Antti J.; Kunkel, Nathalie (2020-09-10). "Borate Hydrides as a New Material Class: Structure, Computational Studies, and Spectroscopic Investigations on Sr 5 (BO 3) 3 H and Sr 5 (11 BO 3) 3 D". Chemistry – A European Journal. 26 (51): 11742–11750. doi:10.1002/chem.202002273. ISSN 0947-6539. PMC 7540042. PMID 32542938.
  15. ^ Gehlhaar, Florian; Finger, Raphael; Zapp, Nicolas; Bertmer, Marko; Kohlmann, Holger (2018-10-01). "LiSr 2 SiO 4 H, an Air-Stable Hydride as Host for Eu(II) Luminescence". Inorganic Chemistry. 57 (19): 11851–11854. doi:10.1021/acs.inorgchem.8b01780. ISSN 0020-1669. PMID 30203971. S2CID 52181350.
  16. ^ Jehle, Michael; Hoffmann, Anke; Kohlmann, Holger; Scherer, Harald; Röhr, Caroline (February 2015). "The 'sub' metallide oxide hydrides Sr 21 Si 2 O 5 H 12 + x and Ba 21 M 2 O 5 H 12 + x (M= Zn, Cd, Hg, In, Tl, Si, Ge, Sn, Pb, As, Sb, Bi)". Journal of Alloys and Compounds. 623: 164–177. doi:10.1016/j.jallcom.2014.09.228.
  17. ^ Mutschke, Alexander; Wylezich, Thomas; Ritter, Clemens; Karttunen, Antti J.; Kunkel, Nathalie (2019-12-31). "An Unprecedented Fully H – -Substituted Phosphate Hydride Sr 5 (PO 4) 3 H Expanding the Apatite Family". European Journal of Inorganic Chemistry. 2019 (48): 5073–5076. doi:10.1002/ejic.201901151. ISSN 1434-1948. S2CID 212948208.
  18. ^ Zapp, Nicolas; Auer, Henry; Kohlmann, Holger (2019-11-04). "YHO, an Air-Stable Ionic Hydride". Inorganic Chemistry. 58 (21): 14635–14641. doi:10.1021/acs.inorgchem.9b02308. ISSN 0020-1669. PMID 31626539. S2CID 204788264.
  19. ^ Plokker, M.P.; Eijt, S.W.H.; Naziris, F.; Schut, H.; Nafezarefi, F.; Schreuders, H.; Cornelius, S.; Dam, B. (April 2018). "Electronic structure and vacancy formation in photochromic yttrium oxy-hydride thin films studied by positron annihilation". Solar Energy Materials and Solar Cells. 177: 97–105. Bibcode:2018SEMSC.177...97P. doi:10.1016/j.solmat.2017.03.011.
  20. ^ Huang, Baoquan; Corbett, John D. (December 1998). "Ba3AlO4H: Synthesis and Structure of a New Hydrogen-Stabilized Phase". Journal of Solid State Chemistry. 141 (2): 570–575. Bibcode:1998JSSCh.141..570H. doi:10.1006/jssc.1998.8022.
  21. ^ a b c Yajima, Takeshi; Takahashi, Kanako; Nakajima, Hotaka; Honda, Takashi; Ikeda, Kazutaka; Otomo, Toshiya; Hiroi, Zenji (2022-01-31). "High-Pressure Synthesis of Transition-Metal Oxyhydrides with Double-Perovskite Structures". Inorganic Chemistry. 61 (4): 2010–2016. doi:10.1021/acs.inorgchem.1c03162. ISSN 0020-1669. PMID 35034444.
  22. ^ Higashi, Kentaro; Ochi, Masayuki; Nambu, Yusuke; Yamamoto, Takafumi; Murakami, Taito; Yamashina, Naoya; Tassel, Cédric; Matsumoto, Yuki; Takatsu, Hiroshi; Brown, Craig M.; Kageyama, Hiroshi (2021-08-16). "Enhanced Magnetic Interaction by Face-Shared Hydride Anions in 6H-BaCrO 2 H". Inorganic Chemistry. 60 (16): 11957–11963. doi:10.1021/acs.inorgchem.1c00992. ISSN 0020-1669. PMID 34309363. S2CID 236432530.
  23. ^ Goto, Yoshihiro; Tassel, Cédric; Noda, Yasuto; Hernandez, Olivier; Pickard, Chris J.; Green, Mark A.; Sakaebe, Hikari; Taguchi, Noboru; Uchimoto, Yoshiharu; Kobayashi, Yoji; Kageyama, Hiroshi (May 2017). "Pressure-Stabilized Cubic Perovskite Oxyhydride BaScO 2 H". Inorganic Chemistry. 56 (9): 4840–4845. doi:10.1021/acs.inorgchem.6b02834. ISSN 0020-1669. PMID 28398729.
  24. ^ Takeiri, Fumitaka; Watanabe, Akihiro; Kuwabara, Akihide; Nawaz, Haq; Ayu, Nur Ika Puji; Yonemura, Masao; Kanno, Ryoji; Kobayashi, Genki (20 February 2019). "Ba2 ScHO3 : H- Conductive Layered Oxyhydride with H- Site Selectivity". Inorganic Chemistry. 58 (7): 4431–4436. doi:10.1021/acs.inorgchem.8b03593. PMID 30784265. S2CID 73480447.
  25. ^ Morgan, Harry W. T.; Yamamoto, Takafumi; Nishikubo, Takumi; Ohmi, Takuya; Koike, Takehiro; Sakai, Yuki; Azuma, Masaki; Ishii, Hirofumi; Kobayashi, Genki; McGrady, John E. (2022-04-22). "Sequential Pressure-Induced B 1– B 2 Transitions in the Anion-Ordered Oxyhydride Ba 2 YHO 3". Inorganic Chemistry. 61 (18): 7043–7050. doi:10.1021/acs.inorgchem.2c00465. ISSN 0020-1669. PMC 9092455. PMID 35451819.
  26. ^ a b c d e f g Jehle, Michael; Hoffmann, Anke; Kohlmann, Holger; Scherer, Harald; Röhr, Caroline (February 2015). "The 'sub' metallide oxide hydrides Sr 21 Si 2 O 5 H 12 + x and Ba 21 M 2 O 5 H 12 + x (M= Zn, Cd, Hg, In, Tl, Si, Ge, Sn, Pb, As, Sb, Bi)". Journal of Alloys and Compounds. 623: 164–177. doi:10.1016/j.jallcom.2014.09.228.
  27. ^ Fjellvåg, Øystein S.; Armstrong, Jeff; Sławiński, Wojciech A.; Sjåstad, Anja O. (2017-09-18). "Thermal and Structural Aspects of the Hydride-Conducting Oxyhydride La 2 LiHO 3 Obtained via a Halide Flux Method". Inorganic Chemistry. 56 (18): 11123–11128. doi:10.1021/acs.inorgchem.7b01409. hdl:10852/69421. ISSN 0020-1669. PMID 28862439.
  28. ^ Ding, Xiang; Tam, Charles C.; Sui, Xuelei; Zhao, Yan; Xu, Minghui; Choi, Jaewon; Leng, Huaqian; Zhang, Ji; Wu, Mei; Xiao, Haiyan; Zu, Xiaotao; Garcia-Fernandez, Mirian; Agrestini, Stefano; Wu, Xiaoqiang; Wang, Qingyuan (2023-03-02). "Critical role of hydrogen for superconductivity in nickelates". Nature. 615 (7950): 50–55. Bibcode:2023Natur.615...50D. doi:10.1038/s41586-022-05657-2. ISSN 0028-0836. PMID 36859583. S2CID 257260047.
  29. ^ Rudolph, Daniel; Enseling, David; Jüstel, Thomas; Schleid, Thomas (2017-11-17). "Crystal Structure and Luminescence Properties of the First Hydride Oxide Chloride with Divalent Europium: LiEu 2 HOCl 2: Crystal Structure and Luminescence Properties of the First Hydride Oxide Chloride with Divalent Europium: LiEu 2 HOCl 2". Zeitschrift für anorganische und allgemeine Chemie. 643 (21): 1525–1530. doi:10.1002/zaac.201700224.
  30. ^ a b c d Widerøe, Marius; Fjellvåg, Helmer; Norby, Truls; Willy Poulsen, Finn; Willestofte Berg, Rolf (July 2011). "NdHO, a novel oxyhydride". Journal of Solid State Chemistry. 184 (7): 1890–1894. Bibcode:2011JSSCh.184.1890W. doi:10.1016/j.jssc.2011.05.025.
  31. ^ Ueda, Jumpei; Matsuishi, Satoru; Tokunaga, Takayuki; Tanabe, Setsuhisa (2018). "Preparation, electronic structure of gadolinium oxyhydride and low-energy 5d excitation band for green luminescence of doped Tb 3+ ions". Journal of Materials Chemistry C. 6 (28): 7541–7548. doi:10.1039/C8TC01682H. ISSN 2050-7526.
  32. ^ Zapp, Nicolas; Sheptyakov, Denis; Franz, Alexandra; Kohlmann, Holger (2021-03-03). "HoHO: A Paramagnetic Air-Resistant Ionic Hydride with Ordered Anions". Inorganic Chemistry. 60 (6): 3972–3979. doi:10.1021/acs.inorgchem.0c03822. ISSN 0020-1669. PMID 33656854. S2CID 232115169.
  33. ^ a b c d Zapp, Nicolas; Sheptyakov, Denis; Kohlmann, Holger (2021-06-26). "Computational Chemistry-Guided Syntheses and Crystal Structures of the Heavier Lanthanide Hydride Oxides DyHO, ErHO, and LuHO". Crystals. 11 (7): 750. doi:10.3390/cryst11070750. ISSN 2073-4352.
  34. ^ Pirez, Cyril; Capron, Mickaël; Jobic, Hervé; Dumeignil, Franck; Jalowiecki-Duhamel, Louise (2011-10-17). "Highly Efficient and Stable CeNiHZOY Nano-Oxyhydride Catalyst for H2 Production from Ethanol at Room Temperature". Angewandte Chemie International Edition. 50 (43): 10193–10197. doi:10.1002/anie.201102617. PMID 21990250.
  35. ^ John M. Haschke Thomas H. Allen: Plutonium Hydride, Sesquioxide and Monoxide Monohydride: Pyrophoricity and Catalysis of Plutonium Corrosion, Journal of Alloys and Compounds, 320, 1, 2001, 58–71, doi:10.1016/S0925-8388(01)00932-X.
  36. ^ Rudolph, Daniel; Enseling, David; Jüstel, Thomas; Schleid, Thomas (17 November 2017). "Crystal Structure and Luminescence Properties of the First Hydride Oxide Chloride with Divalent Europium: LiEu2HOCl2". Zeitschrift für anorganische und allgemeine Chemie. 643 (21): 1525–1530. doi:10.1002/zaac.201700224.
  37. ^ a b c d Wei, Zefeng; Ubukata, Hiroki; Zhong, Chengchao; Tassel, Cédric; Kageyama, Hiroshi (2023-05-09). "Pressure-Induced Anion Order–Disorder Transition in Layered Perovskite Sr2LiHOCl2". Inorganic Chemistry. 62 (20): 7993–8000. doi:10.1021/acs.inorgchem.3c00909. ISSN 0020-1669. PMID 37159274. S2CID 258567534.
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