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Summary

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English: The hydrolysis of the aluminium Lewis acid Al3+aq shows the species concentrations for a 5×10−6M solution of an aluminium salt as a function of pH. Each concentration is shown as a percentage of the total aluminium. The data (available in the talk page) was generated using HySS2009 software application and was plotted using python script given below.
Date 30 July 2014, 13:35:59
Source Own work
Author Krishnavedala
SVG development
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This plot was created with Matplotlib.
Source code
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Python code

Source code
#/usr/bin/python

from numpy import loadtxt
from matplotlib import pyplot as plt

if __name__=="main":
	X = loadtxt("data.txt", skiprows=16)

	fig, ax = plt.subplots(1,1,figsize=(15,10))

	ph = X[:,4]
	Al = X[1,1]
	Al1 = X[:,5] * 100. / Al
	Al2 = X[:,6] * 100. / Al
	Al3 = X[:,7] * 100. / Al
	Al4 = X[:,8] * 100. / Al
	Al5 = X[:,10] * 13 * 100. / Al
	Al6 = X[:,3] * 100. / Al
	Al7 = X[:,12] * 100. / Al

	ax.plot(ph, Al1, linewidth=2, label=r"Al(OH)${}^{2+}$")
	ax.plot(ph, Al2, linewidth=2, label=r"Al(OH)${}_2^+$")
	ax.plot(ph, Al3, linewidth=2, label=r"Al(OH)${}_3$")
	ax.plot(ph, Al4, linewidth=2, label=r"Al(OH)${}_4^-$")
	ax.plot(ph, Al5, linewidth=2, label=r"Al${}_{13}$(OH)${}_{32}^{7+}$")
	ax.plot(ph, Al6, linewidth=2, label=r"Al${}^{3+}$")
	ax.plot(ph, Al7, linewidth=2, label=r"Al(OH)${}_3$(s)")

	ax.set_ylim([0,100])
	ax.grid(True)
	ax.legend(frameon=False, ncol=3, loc=9)
	ax.minorticks_on()
	ax.set_ylabel("% formation relative to Al")
	ax.set_xlabel("pH")

	fig.savefig("Al hydrolysis.svg",bbox_inches="tight", pad_inches=.15)

Licensing

I, the copyright holder of this work, hereby publish it under the following license:
Creative Commons CC-Zero This file is made available under the Creative Commons CC0 1.0 Universal Public Domain Dedication.
The person who associated a work with this deed has dedicated the work to the public domain by waiving all of their rights to the work worldwide under copyright law, including all related and neighboring rights, to the extent allowed by law. You can copy, modify, distribute and perform the work, even for commercial purposes, all without asking permission.

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30 July 2014

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Date/TimeThumbnailDimensionsUserComment
current19:02, 4 January 2018Thumbnail for version as of 19:02, 4 January 20181,133 × 749 (64 KB)Krishnavedalareplotted and manually removed "W3 validation" error causing line
17:44, 30 July 2014Thumbnail for version as of 17:44, 30 July 20141,135 × 794 (74 KB)KrishnavedalaUser created page with UploadWizard

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