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Enhanced weathering

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Enhanced weathering, also termed ocean alkalinity enhancement when proposed for carbon credit systems, is a process that aims to accelerate the natural weathering by spreading finely ground silicate rock, such as basalt, onto surfaces which speeds up chemical reactions between rocks, water, and air. It also removes carbon dioxide (CO2) from the atmosphere, permanently storing it in solid carbonate minerals or ocean alkalinity.[1] The latter also slows ocean acidification.

Enhanced weathering is a chemical approach to remove carbon dioxide involving land-based or ocean-based techniques. One example of a land-based enhanced weathering technique is in-situ carbonation of silicates. Ultramafic rock, for example, has the potential to store hundreds to thousands of years' worth of CO2 emissions, according to estimates.[2][3] Ocean-based techniques involve alkalinity enhancement, such as grinding, dispersing, and dissolving olivine, limestone, silicates, or calcium hydroxide to address ocean acidification and CO2 sequestration.[4]

Although existing mine tailings[5] or alkaline industrial silicate minerals (such as steel slags, construction & demolition waste, or ash from biomass incineration) may be used at first,[6] mining more basalt might eventually be required to limit climate change.[7]

History

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Enhanced weathering has been proposed for both terrestrial and ocean-based carbon sequestration. Ocean methods are being tested by the non-profit organization Project Vesta to see if they are environmentally and economically viable.[8][9]

In July 2020, a group of scientists assessed that the geo-engineering technique of enhanced rock weathering, i.e., spreading finely crushed basalt on fields – has potential use for carbon dioxide removal by nations, identifying costs, opportunities, and engineering challenges.[10][11]

Natural mineral weathering and ocean acidification

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See also: Weathering and Ocean acidification
Stone split by frost weathering on the mountain path to the tongue of the Morteratsch glacier.
Role of carbonate in sea exchange of carbon dioxide.

Weathering is the natural process of rocks and minerals dissolving to the action of water, ice, acids, salts, plants, animals, and temperature changes.[12] It is mechanical (breaking up rock—also called physical weathering or disaggregation) and chemical (changing the chemical compounds in the rocks).[12] Biological weathering is a form of weathering (mechanical or chemical) by plants, fungi, or other living organisms.[12]

Chemical weathering can happen by different mechanisms, depending mainly on the nature of the minerals involved. This includes solution, hydration, hydrolysis, and oxidation weathering.[13] Carbonation weathering is a particular type of solution weathering.[13]

Carbonate and silicate minerals are examples of minerals affected by carbonation weathering. When silicate or carbonate minerals are exposed to rainwater or groundwater, they slowly dissolve due to carbonation weathering: that is the water (H2O) and carbon dioxide (CO2) present in the atmosphere form carbonic acid (H2CO3) by the reaction:[12][14]

H2O + CO2 → H2CO3

This carbonic acid then attacks the mineral to form carbonate ions in solution with the unreacted water. As a result of these two chemical reactions (carbonation and dissolution), minerals, water, and carbon dioxide combine, which alters the chemical composition of minerals and removes CO2 from the atmosphere. Of course, these are reversible reactions, so if the carbonate encounters H ions from acids, such as in soils, they will react to form water and release CO2 back to the atmosphere. Applying limestone (a calcium carbonate) to acid soils neutralizes the H ions but releases CO2 from the limestone[clarification needed].

In particular, forsterite (a silicate mineral) is dissolved through the reaction:

Mg2SiO4(s) + 4H2CO3(aq) → 2Mg2+(aq) + 4HCO3−(aq) + H4SiO4(aq)

where "(s)" indicates a substance in a solid state and "(aq)" indicates a substance in an aqueous solution.

Calcite (a carbonate mineral) is instead dissolved through the reaction:

CaCO3(s) + H2CO3(aq) → Ca2+(aq) + 2HCO3−(aq)

Although some of the dissolved bicarbonate may react with soil acids during the passage through the soil profile to groundwater, water with dissolved bicarbonate ions (HCO3−) eventually ends up in the ocean,[14] where the bicarbonate ions are biomineralized to carbonate minerals for shells and skeletons through the reaction:

Ca2+ + 2HCO3− → CaCO3 + CO2 + H2O

The carbonate minerals then eventually sink from the ocean surface to the ocean floor.[14] Most of the carbonate is redissolved in the deep ocean as it sinks.

Over geological time periods these processes are thought to stabilize the Earth's climate.[15] The ratio of carbon dioxide in the atmosphere as a gas (CO2) to the quantity of carbon dioxide converted into carbonate is regulated by a chemical equilibrium: in case of a change of this equilibrium state, it takes theoretically (if no other alteration is happening during this time) thousands of years to establish a new equilibrium state.[14]

For silicate weathering, the theoretical net effect of dissolution and precipitation is 1 mol of CO2 sequestered for every mol of Ca2+ or Mg2+ weathered out of the mineral. Given that some of the dissolved cations react with existing alkalinity in the solution to form CO32− ions, the ratio is not exactly 1:1 in natural systems but is a function of temperature and CO2 partial pressure. The net CO2 sequestration of carbonate weathering reaction and carbonate precipitation reaction is zero.[clarification needed]

Carbon-silicate cycle feedbacks.

Weathering and biological carbonate precipitation are thought to be only loosely coupled on short time periods (<1000 years). Therefore, an increase in both carbonate and silicate weathering with respect to carbonate precipitation will result in a buildup of alkalinity in the ocean.[clarification needed]

Terrestrial enhanced weathering

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Enhanced weathering was initially used to refer specifically to the spreading of crushed silicate minerals on the land surface.[16][17] Biological activity in soils has been shown to promote the dissolution of silicate minerals,[18] but there is still uncertainty surrounding how quickly this may happen. Because weathering rate is a function of saturation of the dissolving mineral in solution (decreasing to zero in fully saturated solutions), some have suggested that lack of rainfall may limit terrestrial enhanced weathering,[19] although others[20] suggest that secondary mineral formation or biological uptake may suppress saturation and promote weathering.

The amount of energy that is required for comminution depends on the rate at which the minerals dissolve (less comminution is required for rapid mineral dissolution). A 2012 study suggested a large range in potential cost of enhanced weathering largely due to the uncertainty surrounding mineral dissolution rates.[21]

Oceanic enhanced weathering

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To overcome the limitations of solution saturation and to use natural comminution of sand particles from wave energy, silicate minerals may be applied to coastal environments,[22] although the higher pH of seawater may substantially decrease the rate of dissolution,[23] and it is unclear how much comminution is possible from wave action.

Alternatively, the direct application of carbonate minerals to the upwelling regions of the ocean has been investigated.[24] Carbonate minerals are supersaturated in the surface ocean but are undersaturated in the deep ocean. In areas of upwelling, this undersaturated water is brought to the surface. While this technology will likely be cheap, the maximum annual CO2 sequestration potential is limited.

Transforming the carbonate minerals into oxides and spreading this material in the open ocean ('Ocean Liming') has been proposed as an alternative technology.[25] Here the carbonate mineral (CaCO3) is transformed into lime (CaO) through calcination. The energy requirements for this technology are substantial.

Mineral carbonation

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The enhanced dissolution and carbonation of silicates ('mineral carbonation') was first proposed by Seifritz in 1990,[26] and developed initially by Lackner et al.[27] and further by the Albany Research Center.[28] This early research investigated the carbonation of extracted and crushed silicates at elevated temperatures (~180 °C) and partial pressures of CO2 (~15 MPa) inside controlled reactors ("ex-situ mineral carbonation"). Some research explores the potential of "in-situ mineral carbonation" in which the CO2 is injected into silicate rock formations to promote carbonate formation underground (see: CarbFix).

Mineral carbonation research has largely focused on the sequestration of CO2 from flue gas. It could be used for geoengineering if the source of CO2 was derived from the atmosphere, e.g. through direct air capture or biomass-CCS.

Soil Remineralization contributes to the enhanced weathering process. Mixing the soil with crushed rock such as silicate benefits not only plants' health, but also carbon sequestration when calcium or magnesium are present.[29] Remineralize The Earth is a non-profit organization that promotes rock dust applications as natural fertilizers in agriculture fields to restore soils with minerals, improve the quality of vegetation and increase carbon sequestration.

Electrolytic dissolution of silicate minerals

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Where abundant electric surplus electricity is available, the electrolytic dissolution of silicate minerals has been proposed[30] and experimentally shown. The process resembles the weathering of some minerals. In addition, hydrogen produced would be a carbon-negative.[31]

Cost

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In a 2020 techno-economical analysis, the cost of utilizing this method on cropland was estimated at US$80–180 per tonne of CO2. This is comparable with other methods of removing carbon dioxide from the atmosphere currently available (BECCS (US$100–200 per tonne of CO2)- Bio-Energy with Carbon Capture and Storage) and direct air capture and storage at large scale deployment and low-cost energy inputs (US$100–300 per tonne of CO2). In contrast, the cost of reforestation was estimated lower than US$100 per tonne of CO2.[32]

Example projects

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UNDO, a UK-based Enhanced Weathering company, spreads crushed silicate rock, such as basalt and wollastonite, on agricultural land in the United Kingdom, Canada and Australia. They claim to have spread more than 200,000 tonnes of crushed rock to date, which will capture over 40,000 tonnes of CO2 as their rock weathers. In March of 2024, they published a peer-reviewed paper[33] in partnership with Newcastle University in PLOS ONE journal concerning the agronomic co-benefits of crushed basalt in a temperate climate. They are 1 of 20 XPRIZE Carbon Removal[34] finalists, a $100 million competition hosted by the Musk Foundation.

An Irish company named Silicate has run trials in Ireland and in 2023 is running trials in the USA near Chicago. Using concrete crushed down to dust it is scattered on farmland on the ratio 500 tonnes to 50 hectares, aiming to capture 100 tonnes of CO2 per annum from that area. Claiming it improves soil quality and crop productivity, the company sells carbon removal credits to fund the costs. The initial pilot funding comes from prize money awarded to the startup by the THRIVE/Shell Climate-Smart Agriculture Challenge.[35][36]

See also

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References

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    2     production"    . Proceedings of the National Academy of Sciences. 110 (25): 10095–10100. Bibcode:2013PNAS..11010095R. doi:10.1073/pnas.1222358110. PMC 3690887. PMID 23729814.
  32. ^ Beerling, David (2020-07-08). "Potential for large-scale CO2 removal via enhanced rock weathering with croplands". Nature. 583 (7815): 242–248. Bibcode:2020Natur.583..242B. doi:10.1038/s41586-020-2448-9. hdl:10871/122894. PMID 32641817. S2CID 220417075. Archived from the original on 2020-07-16. Retrieved 2021-02-09.
  33. ^ Skov, Kirstine; Wardman, Jez; Healey, Matthew; McBride, Amy; Bierowiec, Tzara; Cooper, Julia; Edeh, Ifeoma; George, Dave; Kelland, Mike E.; Mann, Jim; Manning, David; Murphy, Melissa J.; Pape, Ryan; Teh, Yit A.; Turner, Will (2024-03-27). "Initial agronomic benefits of enhanced weathering using basalt: A study of spring oat in a temperate climate". PLOS ONE. 19 (3): e0295031. Bibcode:2024PLoSO..1995031S. doi:10.1371/journal.pone.0295031. ISSN 1932-6203. PMC 10971544. PMID 38536835.
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