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Agrochemical

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For the football club, see Agrochemical F.C.
The Passaic Agricultural Chemical Works in Newark, New Jersey, 1876

An agrochemical or agrichemical, a contraction of agricultural chemical, is a chemical product used in industrial agriculture. Agrichemical typically refers to biocides (pesticides including insecticides, herbicides, fungicides and nematicides) alongside synthetic fertilizers. It may also include hormones and other chemical growth agents.[1][2] Though the application of mineral fertilizers and pesticidal chemicals has a long history, the majority of agricultural chemicals were developed from the 19th century, and their use were expanded significantly during the Green Revolution and the late 20th century.[3] Agriculture that uses these chemicals is frequently called conventional agriculture.[4]

Agrochemicals are counted among speciality chemicals. Most agrochemicals are products of the petrochemical industry, where chemicals are derivitatives of fossil fuels.[5] The production and use of agrochemicals contribute substantially to climate change, both through direct emissions during production, and through indirect emissions created from soil ecology problems created by the chemicals.[5]

Agrochemicals, especially when improperly used or released in local environments, have led to a number of public health and environmental issues.[3] Agrochemicals and their production can be significant environmental pollution.[3] Agrochemicals are responsible for significant damage to waterways through runoff, and inproperly stored agrochemicals and agrochemical wastes are responsible for spills, especially during extreme weather events.[6][3] Following the publication of Rachel Carson's Silent Spring, increased global attention has been paid to these ecological impacts of certain classes of chemicals, both in terms of effects on ecosystems and biodiversity loss. Some farmers choose not to use agrochemicals, with sustainable agriculture approaches such as organic farming or agroecology, avoiding use of pesticides and industrial chemicals, in favor of naturally occurring chemicals.[7]

Categories

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Biological action

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See also: biological activity

In most of the cases, agrochemicals refer to pesticides.[8]

Application method

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Application process

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Agrochemicals are typically applied to seeds or the field using a variety of different methods.

Seed treatment

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This section is an excerpt from Seed treatment.[edit]

A seed treatment is a treatment of the seed with either chemical agents or biological or by physical methods. Usually done to provide protection to the seed and improve the establishment of healthy crops. Not to be confused with a seed coating.

In agriculture and horticulture, coating of the seed is the process of applying exogenous materials to the seed. Also referred to as seed dressing.

A seed coating is the layer of material added to the seed, which may or may not contain a "protectant" (biological or chemical pesticide) or biostimulant applied to the seed and possibly some color... By the amount of material added, it can be divided into:[9]

  • A Film coating, a layer of thin film applied to the seed typically less than 10% of the mass of the original seed.
  • Encrustment, where the applied material is typically 100%–500% of the original seed mass, but the shape is still discernible.
  • Pellet, where the applied material is so thick that the seed's original shape is not discernible.

Seed coating provides the following functions:

  • For formulations with pesticides, direct application to seeds can be environmentally more friendly, as the amounts used can be very small.[10]
  • Color makes treated seed less attractive to birds, and easier to see and clean up in the case of an accidental spillage.[11]
  • A thick coating can improve handling, by hand or by machine. Thinner coatings may also help with characteristics like flowability.[9]
  • Thick coatings may accommodate additional features such as fertilizers, plant hormones, plant-beneficial microbes, and water-retaining polymers.[9][12]
Specialist machinery is required to safely and efficiently apply the chemical to the seed.[13] A cement mixer is enough for non-hazardous coating materials.[12] The term "seed dressing" is also used to refer to the process of removing chaff, weed seeds and straw from a seed stock.

Sprayers

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This section is an excerpt from Sprayer.[edit]
Folded sprayer
Sprayer partly unfolded
Sprayer fully unfolded
A field sprayer system in folded, partially unfolded and open configuration
Aerial video of a sprayer (unfolding and driving)
A sprayer is a device used to spray a liquid, where sprayers are commonly used for projection of water, weed killers, crop performance materials, pest maintenance chemicals, as well as manufacturing and production line ingredients. In agriculture, a sprayer is a piece of equipment that is used to apply herbicides, pesticides, and fertilizers on agricultural crops. Sprayers range in size from man-portable units (typically backpacks with spray guns) to trailed sprayers that are connected to a tractor, to self-propelled units similar to tractors with boom mounts of 4–30 feet (1.2–9.1 m) up to 60–151 feet (18–46 m) in length depending on engineering design for tractor and land size.[14]

Aerial application

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This section is an excerpt from Aerial application.[edit]
A PZL-106 Kruk crop duster applying a fine mist
A Mil Mi-8 spreading fertilizer

Aerial application, or what is informally referred to as crop dusting,[15] involves spraying crops with crop protection products from an agricultural aircraft. Planting certain types of seed are also included in aerial application. The specific spreading of fertilizer is also known as aerial topdressing in some countries. Many countries have severely limited aerial application of pesticides and other products because of environmental and public health hazards like spray drift; most notably, the European Union banned it outright with a few highly restricted exceptions in 2009,[16] effectively ending the practice in all member states.

Agricultural aircraft are highly specialized, purpose-built aircraft. Today's agricultural aircraft are often powered by turbine engines of up to 1,500 shp (1,100 kW) and can carry as much as 800 US gallons (3,000 L) of crop protection product. Helicopters are sometimes used, and some aircraft serve double duty as water bombers in areas prone to wildfires. These aircraft are referred to as SEAT, or "single engine air tankers."

Ecology

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Main article: Agricultural pollution

Many agrochemicals are toxic, and agrichemicals in bulk storage may pose significant environmental and/or health risks, particularly in the event of accidental spills. In many countries, use of agrichemicals is highly regulated. Government-issued permits for purchase and use of approved agrichemicals may be required. Significant penalties can result from misuse, including improper storage resulting in spillage. On farms, proper storage facilities and labeling, emergency clean-up equipment and procedures, and safety equipment and procedures for handling, application and disposal are often subject to mandatory standards and regulations. Usually, the regulations are carried out through the registration process.

For instance, bovine somatotropin, though widely used in the United States, is not approved in Canada and some other jurisdictions as there are concerns for the health of cows using it.

Impacts of pesticides

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This section is an excerpt from Environmental impact of pesticides.[edit]
A farmworker wearing protective equipment pouring a concentrated pesticide into a sprayer tank with water.
Drainage of fertilizers and pesticides into a stream
Pesticides being sprayed onto a recently plowed field by tractor. Aerial spraying is a main source of pesticide drift and application on loose topsoil increases the chance of runoff into waterways.

The environmental effects of pesticides describe the broad series of consequences of using pesticides. The unintended consequences of pesticides is one of the main drivers of the negative impact of modern industrial agriculture on the environment. Pesticides, because they are toxic chemicals meant to kill pest species, can affect non-target species, such as plants, animals and humans. Over 98% of sprayed insecticides and 95% of herbicides reach a destination other than their target species, because they are sprayed or spread across entire agricultural fields.[17] Other agrochemicals, such as fertilizers, can also have negative effects on the environment.

The negative effects of pesticides are not just in the area of application. Runoff and pesticide drift can carry pesticides into distant aquatic environments or other fields, grazing areas, human settlements and undeveloped areas. Other problems emerge from poor production, transport, storage and disposal practices.[18] Over time, repeat application of pesticides increases pest resistance, while its effects on other species can facilitate the pest's resurgence.[19] Alternatives to heavy use of pesticides, such as integrated pest management, and sustainable agriculture techniques such as polyculture mitigate these consequences, without the harmful toxic chemical application.

Environmental modelling indicates that globally over 60% of global agricultural land (~24.5 million km²) is "at risk of pesticide pollution by more than one active ingredient", and that over 30% is at "high risk" of which a third are in high-biodiversity regions.[20][21] Each pesticide or pesticide class comes with a specific set of environmental concerns. Such undesirable effects have led many pesticides to be banned, while regulations have limited and/or reduced the use of others. The global spread of pesticide use, including the use of older/obsolete pesticides that have been banned in some jurisdictions, has increased overall.[22][23]

History

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Sumerians from 4500 years ago have said to use insecticides in the form of sulfur compounds. Additionally, the Chinese from about 3200 years ago used mercury and arsenic compounds to control the body lice.[24]

Agrochemicals were introduced to protect crops from pests and enhance crop yields. The most common agrochemicals include pesticides and fertilizers.[25] Chemical fertilizers in the 1960s were responsible for the beginning of the "Green Revolution", where using the same surface of land using intensive irrigation and mineral fertilizers such as nitrogen, phosphorus, and potassium has greatly increased food production.[26] Throughout the 1970s through 1980s, pesticide research continued into producing more selective agrochemicals.[24] Due to the adaptation of pests to these chemicals, more and new agrochemicals were being used, causing side effects in the environment.

Companies

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Syngenta was the Chinese owned worldwide leader in agrochemical sales in 2013 at approximately US$10.9 billion, followed by Bayer CropScience, BASF, Dow AgroSciences, Monsanto, and then DuPont with about $3.6 billion.[27] It is still in the worldwide leading position based on sales of year 2019. Based on a statistics by statistica, In 2019, the agrochemical market worldwide was worth approximately $234.2 billion. This is expected to increase to more than $300 billion in 2025.[28]

See also

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References

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  1. ^ "Agrochemicals Handbook from C.H.I.P.S." C.H.I.P.S.
  2. ^ "Agrochemicals and Security". University of Florida. Archived from the original on 2017-10-16. Retrieved 2008-12-14.
  3. ^ a b c d Devi, P. Indira; Manjula, M.; Bhavani, R.V. (2022-10-17). "Agrochemicals, Environment, and Human Health". Annual Review of Environment and Resources. 47 (1): 399–421. doi:10.1146/annurev-environ-120920-111015. ISSN 1543-5938.
  4. ^ Jastrzębska, Magdalena; Kostrzewska, Marta; Saeid, Agnieszka (2022-01-01), Chojnacka, Katarzyna; Saeid, Agnieszka (eds.), "Chapter 1 - Conventional agrochemicals: Pros and cons", Smart Agrochemicals for Sustainable Agriculture, Academic Press, pp. 1–28, ISBN 978-0-12-817036-6, retrieved 2024-10-31
  5. ^ a b Agrochemicals Are Fossil Fuels in Another Form (Report). Center for International Environmental Law (CIEL). 2022-01-01.
  6. ^ Anenberg, Susan C.; Kalman, Casey (May 2019). "Extreme Weather, Chemical Facilities, and Vulnerable Communities in the U.S. Gulf Coast: A Disastrous Combination". GeoHealth. 3 (5): 122–126. doi:10.1029/2019GH000197. ISSN 2471-1403. PMC 7038901. PMID 32159036.
  7. ^ Ganguly, Ram K.; Mukherjee, Arpan; Chakraborty, Susanta K.; Verma, Jay Prakash (2021-01-01), Verma, Jay Prakash; Macdonald, Catriona A.; Gupta, Vijai Kumar; Podile, Appa Rao (eds.), "Chapter 2 - Impact of agrochemical application in sustainable agriculture", New and Future Developments in Microbial Biotechnology and Bioengineering, Elsevier, pp. 15–24, ISBN 978-0-444-64325-4, retrieved 2024-10-31
  8. ^ "Agrochemicals: Types and their effects". worldofchemicals.com. February 2, 2018. Retrieved July 23, 2020.
  9. ^ a b c Pedrini, Simone; Merritt, David J.; Stevens, Jason; Dixon, Kingsley (February 2017). "Seed Coating: Science or Marketing Spin?" (PDF). Trends in Plant Science. 22 (2): 106–116. Bibcode:2017TPS....22..106P. doi:10.1016/j.tplants.2016.11.002. PMID 27979716.
  10. ^ Matthews, G.A. (2000). "Chapter 12: Seed treatment, dust and granule application". Pesticide Application Methods. Blackwell Science Ltd. pp. 253–267. ISBN 0632054735.
  11. ^ Callan, I.W. (1975). "Achievements and limitations of seed treatments". Outl. Agric. 8 (5): 271–274. Bibcode:1975OutAg...8..271C. doi:10.1177/003072707500800504. S2CID 157582780.
  12. ^ a b Rocha, Inês; Ma, Ying; Souza-Alonso, Pablo; Vosátka, Miroslav; Freitas, Helena; Oliveira, Rui S. (6 November 2019). "Seed Coating: A Tool for Delivering Beneficial Microbes to Agricultural Crops". Frontiers in Plant Science. 10: 1357. doi:10.3389/fpls.2019.01357. PMC 6852281. PMID 31781135.
  13. ^ Harris, D.A. (1975). "The application of chemicals to seed". Outl. Agric. 8 (5): 275–280. Bibcode:1975OutAg...8..275H. doi:10.1177/003072707500800505. S2CID 157559918.
  14. ^ "Farm Sprayers Overview". Successful Farming. 2018-01-26. Retrieved 2018-11-21.
  15. ^ "Delta Air Lines | DL | DAL | Heathrow". Heathrow Airport. Retrieved 2022-05-06.
  16. ^ Directive 2009/128/EC of the European Parliament and of the Council of 21 October 2009 establishing a framework for Community action to achieve the sustainable use of pesticides
  17. ^ George Tyler Miller (1 January 2004). Sustaining the Earth: An Integrated Approach. Thomson/Brooks/Cole. pp. 211–216. ISBN 978-0-534-40088-0.
  18. ^ Tashkent (1998), Part 75. Conditions and provisions for developing a national strategy for biodiversity conservation Archived 13 October 2007 at the Wayback Machine. Biodiversity Conservation National Strategy and Action Plan of Republic of Uzbekistan. Prepared by the National Biodiversity Strategy Project Steering Committee with the Financial Assistance of The Global Environmental Facility (GEF) and Technical Assistance of United Nations Development Programme (UNDP). Retrieved on 17 September 2007.
  19. ^ Damalas, C. A.; Eleftherohorinos, I. G. (2011). "Pesticide Exposure, Safety Issues, and Risk Assessment Indicators". International Journal of Environmental Research and Public Health. 8 (12): 1402–19. doi:10.3390/ijerph8051402. PMC 3108117. PMID 21655127.
  20. ^ "A third of global farmland at 'high' pesticide pollution risk". phys.org. Retrieved 22 April 2021.
  21. ^ Tang, Fiona H. M.; Lenzen, Manfred; McBratney, Alexander; Maggi, Federico (April 2021). "Risk of pesticide pollution at the global scale". Nature Geoscience. 14 (4): 206–210. Bibcode:2021NatGe..14..206T. doi:10.1038/s41561-021-00712-5. ISSN 1752-0908.
  22. ^ Lamberth, C.; Jeanmart, S.; Luksch, T.; Plant, A. (2013). "Current Challenges and Trends in the Discovery of Agrochemicals". Science. 341 (6147): 742–6. Bibcode:2013Sci...341..742L. doi:10.1126/science.1237227. PMID 23950530. S2CID 206548681.
  23. ^ Tosi, S.; Costa, C.; Vesco, U.; Quaglia, G.; Guido, G. (2018). "A survey of honey bee-collected pollen reveals widespread contamination by agricultural pesticides". The Science of the Total Environment. 615: 208–218. doi:10.1016/j.scitotenv.2017.09.226. PMID 28968582. S2CID 19956612.
  24. ^ a b Unsworth, John (10 May 2010). "History of Pesticide Use". International Union of Pure and Applied Chemistry.
  25. ^ "Agrochemical". 2 May 2017.
  26. ^ Carvalho, Fernando P. (2006). "Agriculture, pesticides, food security and food safety". Environmental Science & Policy. 9 (7–8). Elsevier BV: 685–692. Bibcode:2006ESPol...9..685C. doi:10.1016/j.envsci.2006.08.002. ISSN 1462-9011.
  27. ^ Agropages.com Mar. 25, 2014 Top six agrochemical firms grew steady in 2013
  28. ^ Statista.com/ July. 6, 2021 Agricultural chemicals market value worldwide in 2018 and 2019 with a forecast from 2020 to 2025
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